NDLI: Atomic line profiles—their measurement and importance in analytical atomic spectroscopy. Invited lecture

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Journal of Analytical Atomic Spectrometry Vol -32

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Journal of Analytical Atomic Spectrometry Vol - 7 Issue - 8

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Journal of Analytical Atomic Spectrometry Vol - 7 Issue - 6

Journal of Analytical Atomic Spectrometry Vol - 7 Issue - 5

Journal of Analytical Atomic Spectrometry Vol - 7 Issue - 4

Journal of Analytical Atomic Spectrometry Vol - 7 Issue - 3

Journal of Analytical Atomic Spectrometry Vol - 7 Issue - 2

XXVII Colloquium Spectroscopicum Internationale: June 9–14, 1991, Bergen, Norway

A personal tribute to Sir Alan Walsh

Sir Alan Walsh—the Scientist and the Man

Atomic absorption spectroscopy—present and future aspects

Reflections and comments from Sir Alan Walsh, FRS

New developments and final frontiers in inductively coupled plasma spectrometry. Plenary lecture

Glow discharge: considerations as a versatile analytical source. Plenary lecture

Microanalysis of individual environmental particles. Plenary lecture

Photon detection based on pulsed, laser-enhanced ionization and photoionization of magnesium vapour: quantum efficiency versus ion yield. Invited lecture

Detection of trace amounts of toxic metals in environmental samples by laser-excited atomic fluorescence spectrometry. Invited lecture

Determination of lead in natural and waste waters using a non-dispersive atomic fluorescence spectrometer with a tungsten spiral atomizer

Precise determination of iron isotope ratios in whole blood using inductively coupled plasma mass spectrometry. Invited lecture

Application of isotope dilution analysis—inductively coupled plasma mass spectrometry to the precise determination of silver and antimony in pure copper

Analysis of conducting solids by inductively coupled plasma mass spectrometry with spark ablation

Rapid and accurate element determination in lubricating oils using inductively coupled plasma optical emission spectrometry

Matrix effects of easily ionized elements on the spatial distribution of electron number densities in an inductively coupled plasma using an optical fibre probe and a photodiode array spectrometer

Monte Carlo study of analyte desorption, adsorption and spatial distribution in electrothermal atomizers. Invited lecture

Effects of modifier mass and temperature gradients on analyte sensitivity in electrothermal atomic absorption spectrometry. Invited lecture

Chemical modification in electrothermal atomic absorption spectrometry. Organization and classification of data by multivariate methods. Invited lecture

Application of radiotracers to methodological studies in atomic absorption spectrometry. Invited lecture

Determination of selenium in staple foods and total diets by electrothermal atomic absorption spectrometry without solvent extraction

Determination of lead by hydride generation and atomization under low pressure using atomic absorption spectrometry

Sensitivity enhancement effects of organic reagents on ytterbium, aluminium and chromium in atomic absorption spectrometry

Determination of vanadium in vegetable matter by flame atomic absorption spectrometry

Column preconcentration of iron(III) with an ion pair of 1,2-dihydroxybenzene-3,5-disulfonate and benzyldimethyltetradecylammonium ion supported on naphthalene using flame atomic absorption spectrometry

Determination of some trace elements in sea-water by atomic absorption spectrometry after concentration with modified silicas

Selective determination of toxicologically important arsenic species in urine by high-performance liquid chromatography–hydride generation atomic absorption spectrometry

Nitrogen-selective detection for gas chromatography with a helium radiofrequency plasma detector. Invited lecture

Microwave-induced plasma as an element-specific detector for speciation studies at the trace level. Invited lecture

Analyte volatilization procedure for continuous-flow determination of bromine by atmospheric pressure helium microwave-induced plasma atomic emission spectrometry

Considerations in the gas flow design of a graphite furnace vaporization interface: effects of a halocarbon atmosphere and sample matrix. Invited lecture

Direct analysis of liquid and solid samples without sample preparation using laser-enhanced ionization

Evaluation of a gas jet-enhanced sputtering device for atomic absorption spectrometry

Boron, calcium and silicon in an arc plasma in air with chlorine: calculation of the plasma composition

Quantitative depth profiling of oxide scales on high-temperature alloys by means of glow discharge optical emission spectrometry

Analytical system for the analysis of ferrovanadium using spark ablation coupled with inductively coupled plasma atomic emission spectrometry

Quantitative analysis of glass using inductively coupled plasma atomic emission and mass spectrometry, laser micro-analysis inductively coupled plasma atomic emission spectrometry and laser ablation inductively coupled plasma mass spectrometry

Methods for the detection of single atoms using optical and mass spectrometry. Invited lecture

Quantitative analysis of steel samples with laser ionization mass spectrometry

Atomic line profiles—their measurement and importance in analytical atomic spectroscopy. Invited lecture

Total reflection X-ray fluorescence—an efficient method for micro-, trace and surface layer analysis. Invited lecture

Principles and applications of energy-dispersive X-ray fluorescence analysis with polarized radiation

Flow injection–electrochemical hydride generation technique for atomic absorption spectrometry. Invited lecture

Critical evaluation of the efficiency and synergistic effects of flow injection techniques for sensitivity enhancement in flame atomic absorption spectrometry

Flow injection systems for directly coupling on-line digestions with analytical atomic spectrometry. Part 1. Dissolution of cocoa under stopped-flow, high-pressure conditions

Quartz tube atomizers for hydride generation atomic absorption spectrometry: mechanism for atomization of arsine. Invited lecture

Determination of arsenic in a nickel-based alloy by flow injection hydride generation atomic absorption spectrometry incorporating continuous-flow matrix isolation and stopped-flow pre-reduction procedures

Flow injection flame atomic absorption spectrometric determination of copper with preconcentration on ligand loaded amberlite XAD-2

Protocol for the design and interpretation of method evaluation in atomic absorption spectrometric analysis. Application to the determination of lead and manganese in blood

On-line gradient calibration for atomic absorption spectrometry

Excitation and detection of molecular species with furnace atomization plasma emission spectrometry

Thermal disequilibrium effects in a molecular glow discharge

Atomization mechanisms of silicon in a graphite furnace atomizer

Investigations of gas-flow patterns within a cylindrical glass tube having dimensions identical with those of a graphite furnace atomizer under the influence of forced convective flow

Aluminium atom formation in electrothermal graphite atomizer atomic absorption spectrometry studied by in situ spectroscopic measurements of aluminium and aluminium hydride

Simplified kinetic model describing the analyte losses during pre-atomization thermal treatment in electrothermal atomic absorption spectrometry

Mechanisms of chloride interferences in atomic absorption spectrometry using a graphite furnace atomizer investigated by electrothermal vaporization inductively coupled plasma mass spectrometry. Part 1. Effect of magnesium chloride matrix and ascorbic acid chemical modifier on manganese

Direct determination of cadmium in sea-water using electrothermal atomization atomic absorption spectrometry with Zeeman-effect background correction and oxalic acid as a chemical modifier

Application of palladium as a chemical modifier in electrothermal atomic absorption spectrometry with a tungsten tube atomizer

Chemical modification and spectral interferences in selenium determination using Zeeman-effect electrothermal atomic absorption spectrometry

Determination of total mercury in human whole blood by electrothermal atomic absorption spectrometry following extraction

Vapour-phase behaviour of slurries in electrothermal atomic absorption spectrometry

Determination of beryllium in coal fly ash by electrothermal atomic absorption spectrometry

Determination of tin by electrothermal atomic absorption spectrometry with a tungsten-coated tube

Determination of cadmium in environmental samples by electrothermal atomic absorption spectrometry using a tantalum-foil platform with the possibility of standardless analysis

Combination of flow injection hydride generation and sequestration on a graphite tube for the automated determination of antimony in potable and surface waters

Flow injection on-line coprecipitation preconcentration for electrothermal atomic absorption spectrometry

Determination of alkylselenides by gas chromatography–electrothermal atomic absorption spectrometry

Detection of technetium in electrothermal atomic absorption spectrometry using coincident emission lines of other elements

Radiation-enhanced field-forced deposition of a laser-produced aerosol in a graphite furnace and continuum-source coherent forward scattering multi-element determination

Computer program (CHMASS) for calculating theoretical characteristic mass values in electrothermal atomic absorption spectrometry

XXVII-CSI Pre-Symposium: graphite atomizer techniques in analytical spectroscopy. Discussion—modelling of graphite furnace processes: what do we know?

Cumulative author index

Journal of Analytical Atomic Spectrometry Vol - 7 Issue - 1

Journal of Analytical Atomic Spectrometry Vol -6

Journal of Analytical Atomic Spectrometry Vol -5

Journal of Analytical Atomic Spectrometry Vol -4

Journal of Analytical Atomic Spectrometry Vol -2

Atomic line profiles—their measurement and importance in analytical atomic spectroscopy. Invited lecture

Content Provider	Royal Society of Chemistry (RSC)
Author	Larkins, Peter L.
Copyright Year	1992
Abstract	Profiles of the resonance lines of Ag, Co, Hg, Mn, Mg and Pt, emitted by hollow cathode lamps (HCLs), have been measured for a range of currents using a scanning échelle monochromator. The effect on the calibration graph of self-absorption broadening or self-reversal due to higher currents is complex and is strongly influenced by the presence of isotope and hyperfine structure. The échelle monochromator has also been used to measure absorption linewidths and shifts in the air–acetylene flame, and results obtained for Ag, Li, Mg and Mn were found to be in good agreement with calculated values reported in the literature. For Li, the use of a semiconductor laser diode instead of a hollow cathode light source is shown to overcome some of the inherent disadvantages of the HCL and to provide improved sensitivity and better linearity.
Starting Page	265
Ending Page	272
Page Count	8
File Format	PDF
ISSN	02679477
Volume Number	7
Issue Number	2
Journal	Journal of Analytical Atomic Spectrometry
DOI	10.1039/JA9920700265
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	HCL Li Resonance Cathode Echelle grating Monochromator Graph of a function Isotope Hyperfine structure Laser diode Diode
Content Type	Text
Resource Type	Article
Subject	Spectroscopy Analytical Chemistry

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