NDLI: Analytical applications of furnace atomic non-thermal excitation spectrometry (FANES) and molecular non-thermal excitation spectrometry (MONES). Part. 5. Study of the MONES of PO and HPO for the determination of trace amounts of phosphorus

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Journal of Analytical Atomic Spectrometry Vol -4

Journal of Analytical Atomic Spectrometry Vol -2

Analytical applications of furnace atomic non-thermal excitation spectrometry (FANES) and molecular non-thermal excitation spectrometry (MONES). Part. 5. Study of the MONES of PO and HPO for the determination of trace amounts of phosphorus

Content Provider	Royal Society of Chemistry (RSC)
Author	Fuchs, Holger Dittrich, Klaus
Copyright Year	1990
Abstract	A method for the determination of phosphorus by the molecular non-thermal excitation spectrometry (MONES) of PO and HPO has been developed. The phosphorus was introduced into the furnace atomic non-thermal excitation spectrometry (FANES) source as a solution of sodium dihydrogen phosphate. The measurements were carried out at the bands that gave the maximum signals, for PO at 246.4 nm and for HPO at 507 nm. The electrical, thermal and chemical conditions were optimised and are discussed. In addition, the influence of La3+ as a chemical modifier on the MONES of PO and HPO was investigated. The best values for the detection limit were 700 pg of P (MONES of PO) and 3400 pg of P (MONES of HPO). By comparison with the best values obtained with commercial electrothermal atomisation atomic absorption spectrometry instruments, these values are better by factors of 8 and 1.6, respectively. However, the determination of P by FANES at 213.5/213.6 nm is the best method for investigations of phosphorus using the FANES source, in the presence of La3+ as a chemical modifier.
Starting Page	39
Ending Page	43
Page Count	5
File Format	PDF
ISSN	02679477
Volume Number	5
Issue Number	1
Journal	Journal of Analytical Atomic Spectrometry
DOI	10.1039/JA9900500039
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	FANES Phosphorus Monosodium phosphate Absorption spectroscopy
Content Type	Text
Resource Type	Article
Subject	Spectroscopy Analytical Chemistry

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