NDLI: A microporous Cu<sup>2+</sup> MOF based on a pyridyl isophthalic acid Schiff base ligand with high CO<sub>2</sub> uptake

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Inorganic Chemistry Frontiers Vol - 3 Issue - 9

Inorganic Chemistry Frontiers Vol - 3 Issue - 8

Inorganic Chemistry Frontiers Vol - 3 Issue - 7

Inorganic Chemistry Frontiers Vol - 3 Issue - 6

Inorganic Chemistry Frontiers Vol - 3 Issue - 5

Inorganic Chemistry Frontiers Vol - 3 Issue - 4

Inorganic Chemistry Frontiers Vol - 3 Issue - 3

Inorganic Chemistry Frontiers Vol - 3 Issue - 2

Inorganic Chemistry Frontiers Vol -2

Inorganic Chemistry Frontiers Vol -1

A microporous Cu²⁺ MOF based on a pyridyl isophthalic acid Schiff base ligand with high CO₂ uptake

Content Provider	Royal Society of Chemistry (RSC)
Author	Trikalitis, Pantelis N. Tasiopoulos, Anastasios J. Charalambopoulou, Georgia Kourtellaris, Andreas Steriotis, Theodore A. Tampaxis, Christos Spanopoulos, Ioannis Papaefstathiou, Giannis S. Moushi, Eleni E.
Copyright Year	2016
Abstract	A new Cu2+ complex that was isolated from the initial use of 5-((pyridin-4-ylmethylene)amino)isophthalic acid (PEIPH2) in 3d metal–organic framework (MOF) chemistry is reported. Complex {[Cu3(PEIP)2(5-NH2-mBDC)(DMF)]·7DMF}∞ denoted as Cu-PEIP·7DMF was isolated from the reaction of Cu(NO3)2·2.5H2O with PEIPH2 in N,N-dimethylformamide (DMF) at 100 °C and contains both the PEIP2− ligand and its 5-NH2-mBDC2− fragment. After the structure and properties of Cu-PEIP were known an analogous complex was prepared by a rational synthetic method that involved the reaction of Cu(NO3)2·2.5H2O, 5-((pyridin-4-ylmethyl)amino)isophthalic acid (PIPH2 – the reduced analogue of PEIPH2) and 5-NH2-mBDCH2 in DMF at 100 °C. Cu-PEIP comprises two paddle-wheel [Cu2(COO)4] units and exhibits a 3D-framework with a unique trinodal underlying network and point symbol (4.52)4(42·54·64·83·92)2(52·84). This network consists of pillared kgm-a layers containing a hexagonal shaped cavity with a relatively large diameter of ∼8–9 Å surrounded by six trigonal shaped ones with a smaller diameter of ∼4–5 Å and thus resembles the structure of HKUST-1. Gas sorption studies revealed that Cu-PEIP exhibits a 1785 m2 g−1 BET area as well as high CO2 sorption capacity (4.75 mmol g−1 at 273 K) and CO2/CH4 selectivity (8.5 at zero coverage and 273 K).
Starting Page	1527
Ending Page	1535
Page Count	9
File Format	HTM / HTML PDF
ISSN	20521553
Volume Number	3
Issue Number	12
Journal	Inorganic Chemistry Frontiers
DOI	10.1039/c6qi00273k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	BET Carboxylic acid Organic chemistry Dimethylformamide Ligand Chief operating officer Sorption
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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A microporous Cu2+ MOF based on a pyridyl isophthalic acid Schiff base ligand with high CO2 uptake

Selective CO₂ adsorption in a microporous metal–organic framework with suitable pore sizes and open metal sites

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A microporous Cu²⁺ MOF based on a pyridyl isophthalic acid Schiff base ligand with high CO₂ uptake

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