NDLI: Assembly, structures, photophysical properties and photocatalytic activities of a series of coordination polymers constructed from semi-rigid bis-pyridyl-bis-amide and benzenetricarboxylic acid

Please wait, while we are loading the content...

Assembly, structures, photophysical properties and photocatalytic activities of a series of coordination polymers constructed from semi-rigid bis-pyridyl-bis-amide and benzenetricarboxylic acid

A two-dimensional flexible porous coordination polymer based on Co(ii) and terpyridyl phosphine oxide

Guest dependent reversible single-crystal to single-crystal structural transformation in a flexible Gd(iii)-coordination polymer

Field-induced dynamic magnetic behaviour of a canted weak ferromagnetic chain material

Back cover

Inorganic Chemistry Frontiers Vol - 2 Issue - 3

Inorganic Chemistry Frontiers Vol - 2 Issue - 2

Inorganic Chemistry Frontiers Vol -1

Assembly, structures, photophysical properties and photocatalytic activities of a series of coordination polymers constructed from semi-rigid bis-pyridyl-bis-amide and benzenetricarboxylic acid

Content Provider	Royal Society of Chemistry (RSC)
Author	Le, Mao Liu, Guo-Cheng Luan, Jian Sui, Fang-Fang Chang, Zhi-Han Lin, Hong-Yan Wang, Xiuli
Copyright Year	2015
Abstract	A series of new metal(II)–organic coordination polymers, namely [Co(3-DPNA)(1,3,5-HBTC)]·2H2O (1), [Ni(3-DPNA)1.5(1,3,5-HBTC)(H2O)2] (2), [Cu(3-DPNA)(1,3,5-HBTC)]·H2O (3), [Zn(3-DPNA)(1,3,5-HBTC)]·2H2O (4), [Cd(3-DPNA)(1,3,5-HBTC)(H2O)]·2H2O (5), [Co(4-DPNA)(1,3,5-HBTC)]·4H2O (6), [Ni(4-DPNA)(1,3,5-BTC)2/3] (7), [Cu(4-DPNA)(1,3,5-BTC)2/3] (8), [Zn(4-HDPNA)(1,3,5-BTC)] (9), [Cd(4-DPNA)(1,3,5-BTC)1/3Cl] (10), have been purposefully synthesized under hydrothermal conditions [N1,N4-di(pyridin-3-yl)naphthalene-1,4-dicarboxamide (3-DPNA) and N1,N4-di(pyridin-4-yl)naphthalene-1,4-dicarboxamide (4-DPNA), 1,3,5-H3BTC = 1,3,5-benzenetricarboxylic acid]. Complexes 1 and 4 exhibit similar 1D belt-like chains constructed from 1D left- and right-hand [Co-(3-DPNA)]n helical chains and [Co-(1,3,5-HBTC)]n linear chains. Complex 2 furnishes a 1D [Ni-(3-DPNA)1.5]n “loop + line” chain with 1,3,5-HBTC anions hanging on both sides. Complex 3 features a 2D sql network based on [Cu-(3-DPNA)]nmeso-helical chains and [Cu-(1,3,5-HBTC)]n linear chains. Complex 5 shows a 1D ladder-like chain constructed from [Cd-1,3,5-HBTC]n linear chains and [Cd2(3-DPNA)2] loops. Complex 6 displays a 2D double sheet containing (H2O)8 clusters. Complexes 7 and 8 possess similar 3D (3,4)-connected frameworks with the (63)2(64·8·10)3 topology containing a dodecagon-shape cavity and a hexagonal cavity, respectively. Complex 9 shows a 2D network, in which one pyridine nitrogen atom of 4-DPNA was protonated. Complex 10 is a 3D (3,5)-connected framework with (3·44·63·82)3(63) topology. All the 1D chains and 2D networks are further extended into 2D supramolecular sheets or 3D supramolecular frameworks through hydrogen-bonding interactions. The influence of metal(II) ions and N-donor ligands on the structures of the title compounds was investigated. The results suggest that the central metals with various coordination nature and the semi-rigid bis-pyridyl-bis-amide ligands with different coordination sites show a great effect on the structures of the title compounds. In addition, the fluorescence sensing properties of 4, 5, 9, and 10 and the photocatalytic activities of complexes 1–10 have been investigated in detail, and the results show that 5 possesses good fluorescence selectivity for different solvent molecules.
Starting Page	373
Ending Page	387
Page Count	15
File Format	HTM / HTML PDF
ISSN	20521553
Volume Number	2
Issue Number	4
Journal	Inorganic Chemistry Frontiers
DOI	10.1039/c4qi00218k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Water of crystallization Hydrothermal circulation Group N Naphthalene Dicarboximide fungicides Acid Three-dimensional space Topology Pyridine Nitrogen Fluorescence Solvent
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Assembly, structures, photophysical properties and photocatalytic activities of a series of coordination polymers constructed from semi-rigid bis-pyridyl-bis-amide and benzenetricarboxylic acid

Three 2 D copper(II)/cadmium(II) coordination polymers based on semi-rigid/flexible bis-pyridyl-bis-amide ligands and 5-aminoisophthalate: Syntheses, structures and properties

Assembly and properties of transition-metal coordination polymers based on semi-rigid bis-pyridyl-bis-amide ligand : effect of polycarboxylates on the dimensionality

The assembly of thiophene-based bis-pyridyl-bis-amide CoII coordination polymers and their polypyrrole-functionalized hybrid materials for boosting their photocatalytic performances.

Rigid versus semi-rigid bis(imidazole) ligands in the assembly of two Co(ii) coordination polymers: structural variability, electrochemical properties and photocatalytic behavior

Coordination Polymers Constructed from Semi-Rigid N,N′-Bis(3-pyridyl)terephthalamide and Dicarboxylic Acids: Effect of Ligand Isomerism, Flexibility, and Identity

Structural Diversity and Properties of Six ZnII/CdII Coordination Polymers Based on an O-Bridged Semi-Rigid Bis-pyridyl-bis-amide and Different Dicarboxylates

Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates

The design and construction of a series of metal–organic coordination polymers based on two isomeric semi-rigid bis-pyridyl-bis-amide ligands and three aromatic polycarboxylates

Assembly, structures, photophysical properties and photocatalytic activities of a series of coordination polymers constructed from semi-rigid bis-pyridyl-bis-amide and benzenetricarboxylic acid

Similar Documents

Assembly, structures, photophysical properties and photocatalytic activities of a series of coordination polymers constructed from semi-rigid bis-pyridyl-bis-amide and benzenetricarboxylic acid

Three 2 D copper(II)/cadmium(II) coordination polymers based on semi-rigid/flexible bis-pyridyl-bis-amide ligands and 5-aminoisophthalate: Syntheses, structures and properties

Assembly and properties of transition-metal coordination polymers based on semi-rigid bis-pyridyl-bis-amide ligand : effect of polycarboxylates on the dimensionality

The assembly of thiophene-based bis-pyridyl-bis-amide CoII coordination polymers and their polypyrrole-functionalized hybrid materials for boosting their photocatalytic performances.

Rigid versus semi-rigid bis(imidazole) ligands in the assembly of two Co(ii) coordination polymers: structural variability, electrochemical properties and photocatalytic behavior

Coordination Polymers Constructed from Semi-Rigid N,N′-Bis(3-pyridyl)terephthalamide and Dicarboxylic Acids: Effect of Ligand Isomerism, Flexibility, and Identity

Structural Diversity and Properties of Six ZnII/CdII Coordination Polymers Based on an O-Bridged Semi-Rigid Bis-pyridyl-bis-amide and Different Dicarboxylates

Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates

The design and construction of a series of metal–organic coordination polymers based on two isomeric semi-rigid bis-pyridyl-bis-amide ligands and three aromatic polycarboxylates

Assembly, structures, photophysical properties and photocatalytic activities of a series of coordination polymers constructed from semi-rigid bis-pyridyl-bis-amide and benzenetricarboxylic acid