NDLI: Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over MnO<sub><i>x</i></sub>

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Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over MnO_x–CeO₂ composite catalysts

Content Provider	Royal Society of Chemistry (RSC)
Author	Wang, Yanqin Han, Xuewang Xia, Qineng Li, Chaoqun Liu, Xiaohui
Copyright Year	2017
Abstract	The selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) has attracted much attention recently, as FDCA could be used as a polymer precursor to produce recyclable bio-based polymers. But most studies focused on the design of noble metal catalysts for the efficient oxidation of HMF to FDCA, here, non-noble metal catalysts, MnOx–CeO2 mixed oxides, were prepared by a co-precipitation method and used in the direct aerobic oxidation of HMF to FDCA. As high as 91% yield of FDCA was achieved over the MC-6 (Mn/Ce = 6) catalyst and the catalyst can be reused five times without much loss of catalytic activity, this is the best result for non-noble metal catalyzed HMF oxidation to FDCA in the aqueous phase. Structural analysis revealed that surface Mn4+ ions are the active sites and play key roles for the oxidation of HMF in the absence of noble metals. In addition, the reaction mechanism over the MnOx–CeO2 catalyst was also proposed based on the synergistic interaction between Mn and Ce oxides.
Starting Page	996
Ending Page	1004
Page Count	9
File Format	HTM / HTML PDF
ISSN	14639262
Volume Number	19
Issue Number	4
Journal	Green Chemistry
DOI	10.1039/c6gc03304k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	FDCA HMF Hydroxymethylfurfural Acid catalysis Polymer Noble metal Coprecipitation Oxygen Compact Cassette Reaction mechanism
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Pollution

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