NDLI: Dielectric properties of glycerol in the range 0.1–10<sup>5</sup> Hz, 218–357 K, 0

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Front cover

Contents pages

Glass and other relaxations in liquids

Dielectric study of the motion of molecules in the supercooled liquid state

Dielectric properties of glycerol in the range 0.1–10⁵ Hz, 218–357 K, 0–53 kb

General discussion ( Faraday Symposia of the Chemical Society Vol -6 )

Rotational diffusion in para-azoxyanisole

Lattice defects in plastic organic crystals. Part 8.—Self-diffusion and the isotope mass effect in single crystals of 2,2′,3,3′-tetramethylbutane

General discussion ( Faraday Symposia of the Chemical Society Vol -6 )

Molecular motions in liquids: comparison of light scattering and infra-red absorption

Environmental fluctuations and rotational processes in liquids

General discussion ( Faraday Symposia of the Chemical Society Vol -6 )

Interpretation of dipole correlation functions in some liquid systems

Molecular acoustics. Part 8.—Conformational changes in heterocyclic molecules studied by the ultrasonic method

General discussion ( Faraday Symposia of the Chemical Society Vol -6 )

Molecular motions in simple liquids

Molecular dynamics of liquids in relation to the solid and gas phases as seen by neutron scattering

High frequency dynamics of liquid methanol and toluene. Contribution of molecular rotational diffusion to inelastic neutron scattering

General discussion ( Faraday Symposia of the Chemical Society Vol -6 )

Motional broadening of the quasi-elastic peak in neutrons scattered from polymeric materials

Study of molecular motion in solutions of biopolymers using nuclear magnetic resonance

Mechanical techniques for studying viscoelastic relaxation processes in polymer solutions

General discussion ( Faraday Symposia of the Chemical Society Vol -6 )

Author index

Dielectric properties of glycerol in the range 0.1–10⁵ Hz, 218–357 K, 0–53 kb

Content Provider	Royal Society of Chemistry (RSC)
Author	Whalley, E. Johari, G. P.
Copyright Year	1972
Abstract	The dielectric constant and loss of glycerol has been measured in the range 0.1–105 Hz, 218–357 K, and 0–53 kb. A piston-cylinder apparatus was used for the range 0–25 kb and an anvil apparatus for the range 25–53 kb. The static dielectric constant increases with increasing density at a rate that indicates that ∂ln gµ20/∂ ln ρ, where g is Kirkwood's correlation parameter, µ0 the dipole moment of an isolated molecule, and ρ the density, is –0.2. The dispersion region broadens with increasing pressure, and a high-frequency dispersion can be resolved at the higher pressures and lower temperatures. The frequency of maximum loss ƒm decreases with increasing pressure at an increasing rate, a behaviour which is clearly related to the approach to the glass transition. Isotherms can be fitted to the equation ln ƒm=A–B/(p0–P) where A, B and p0 are constants and p0 is the pressure at which ƒm extrapolates to zero.
Starting Page	23
Ending Page	41
Page Count	19
File Format	PDF
ISSN	03015696
Volume Number	6
Journal	Faraday Symposia of the Chemical Society
DOI	10.1039/FS9720600023
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Kirkwood Relative permittivity Glycerol Anvil Kirkwood Mountain Resort Dipole Dispersion relation Glass transition
Content Type	Text
Resource Type	Article

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Dielectric properties of glycerol in the range 0.1–10⁵ Hz, 218–357 K, 0–53 kb

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Dielectric properties of glycerol in the range 0.1–105 Hz, 218–357 K, 0–53 kb

Dielectric properties of glycerol in the range 0.1–10⁵ Hz, 218–357 K, 0–53 kb