NDLI: Copper(ii) 5-methoxyisophthalate coordination polymers incorporating dipyridyl co-ligands: syntheses, crystal structures, and magnetic properties

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Dalton Transactions Vol - 39 Issue - 8

Dalton Transactions Vol - 39 Issue - 7

Dalton Transactions Vol - 39 Issue - 6

Dalton Transactions Vol - 39 Issue - 5

Dalton Transactions Vol -0

Copper(ii) 5-methoxyisophthalate coordination polymers incorporating dipyridyl co-ligands: syntheses, crystal structures, and magnetic properties

Content Provider	Royal Society of Chemistry (RSC)
Author	Liu, Bin Ma, Lu-Fang Li, Cheng-Peng Du, Miao Wang, Li-Ya
Copyright Year	2010
Abstract	Hydrothermal reactions of mixed ligands 5-methoxyisophthalate (CH3O-H2ip) and dipyridyl with Cu(OAc)2·2H2O afford five new coordination polymers, including {[Cu(CH3O-ip)(bpa)]·H2O}n (1), [Cu2(CH3O-ip)2(bpa)0.5(H2O)]n (2), [Cu2(CH3O-ip)2(bpp)(H2O)]n (3), {[Cu3(CH3O-ip)3(bpp)2(H2O)]·3H2O}n (4) and [Cu4(CH3O-ip)3(bpe)(OH)2]n (5) (bpp = 1,3-di(4-pyridyl)propane, bpa = 1,2-bi(4-pyridyl)ethane, and bpe = 1,2-di(4-pyridyl)ethylene). Compound 1 consists of CH3O-ip anion-bridged 1D CuII chains that are linked by trans-bpa into a 2D layer. Compound 2 is a 2D (4,4) layer that is connected by CH3O-ip anions. The gauche bpa in 2 lies in the cavity and meets the coordination requirement of the paddle-wheel dimeric copper unit. Compound 3 is an extended 3D polythreading network consisting of 2D (4,4) motifs with dangling bpp lateral arms. Compound 4 exhibits a 3D (4,6)-connected self-penetrating (65.8)(614.8) network that is composed of binuclear and mononuclear metal nodes. Compound 5 exhibits a 3D network with the tetranuclear [Cu4(μ3-OH)2]6+ cluster acting as nodes, which is constructed by the interconnection of 2D helical layers via bpe pillars. The results of magnetic determination show that the syn–anti carboxylato bridges in our cases induce a weak antiferromagnetic interaction in 1, and the syn–syn carboxylato bridge in 3 and 4 mediates a strong antiferromagnetic interaction.
Starting Page	2301
Ending Page	2308
Page Count	8
File Format	HTM / HTML PDF
ISSN	14779226
Volume Number	39
Issue Number	9
Journal	Dalton Transactions
DOI	10.1039/b920308g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Water of crystallization Propane Ethylene Copper Three-dimensional space Antiferromagnetism
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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