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Dalton Transactions Vol - 0 Issue - 5

Combination of POMs and deliberately designed macrocations: a rational approach for synthesis of POM-pillared metal–organic framework

Content Provider	Royal Society of Chemistry (RSC)
Author	Lan, Ya-Qian Su, Zhong-Min Hao, Xiang-Rong Li, Shun-Li Wang, Xin-Long Shao, Kui-Zhan
Copyright Year	2009
Abstract	Two POM-pillared 3D porous compounds, [CuICuII(CuIIfcz)2(H2O)5(PMoVI10MoV2O40)]·6H2O (1) and [CuI2(CuIIfcz)2(H2O)2(PMoVI8VV3VIV3O42)]·6H2O (2) (Hfcz = fluconazole, (1-(2,4-difluorophenyl)-1,1-bis[(1H-1,2,4-triazol-1-yl)methyl]benzyl alcohol) have been constructed based on different polyanions, (Cufcz)22+ macrocations and copper cations by the hydrothermal method. The (Cufcz)22+ macrocations link Cu cations to generate a 2D wavelike cationic sheet. Then the POM anions act as pillars to the cationic sheet to form different POM-pillared 3D frameworks. In compound 1, the polyanion exhibits a rare coordination mode and acts as a penta-dentate ligand, which acts as to pillars to the cationic sheet to form an unprecedented 3D (3,4,5,6)-connected open framework with (3·6·7)(32·6·73)(33·4·62·73·8)(34·42·62·76·8)(32·62·76·84·10) topology. In compound 2, polyanions covalently link cationic sheets to extend to an unusual 3D (3,4,6)-connected framework with the (52·6)(52·62·7·9)(54·64·74·93) topology. To the best of our knowledge, it is the first time that POM-pillared 3D metal–organic frameworks have been realized by combining POMs with deliberately designed macrocations and transition-metal ions, using a rational approach for synthesis of POM-based open metal–organic frameworks. In addition, the electrochemical behaviors of compounds 1 and 2 have been investigated.
Starting Page	940
Ending Page	947
Page Count	8
File Format	HTM / HTML PDF
ISSN	14779226
Volume Number	0
Issue Number	6
Journal	Dalton Transactions
DOI	10.1039/b810287b
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Water of crystallization Fluconazole Benzyl alcohol Copper Hydrothermal circulation Polyatomic ion Ligand Topology Electrochemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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