NDLI: Thermal expansion in BaRuO<sub>3</sub> perovskites – an unusual case of bond strengthening at high temperatures

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Thermal expansion in BaRuO₃ perovskites – an unusual case of bond strengthening at high temperatures

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Dalton Transactions Vol - 46 Issue - 8

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Thermal expansion in BaRuO₃ perovskites – an unusual case of bond strengthening at high temperatures

Content Provider	Royal Society of Chemistry (RSC)
Author	Hasegawa, Masashi Kayser, Paula Shirako, Yuichi Kennedy, Brendan J. Injac, Sean Oliveira, Andre L. Menezes de
Copyright Year	2017
Abstract	The temperature dependences of the structures of three polytypes of BaRuO3 have been investigated between room temperature and 1000 °C using high resolution synchrotron X-ray diffraction. The structural studies reveal a systematic decrease of the Ru–Ru distance as the pressure required to prepare the polytype increases. The O–O distance across the shared face increases as the Ru–Ru separation decreases. The 9R and 4H polytypes undergo unexceptional changes with increasing temperature. In 6H-BaRuO3 there is an apparent increase in the Ru–Ru interaction at around 650 °C and a concurrent reduction in the O–O distance, indicating an anomalous strengthening of the Ru–Ru interactions upon heating.
Starting Page	2974
Ending Page	2980
Page Count	7
File Format	HTM / HTML PDF
ISSN	14779226
Volume Number	46
Issue Number	9
Journal	Dalton Transactions
DOI	10.1039/c6dt04473e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Synchrotron X-ray crystallography Polymorphism (materials science)
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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