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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Viestel, Bernardo de Oliveira Hartmann, Nils Hagemann, Ulrich Aggarwal, A. Vikas Lutz, Harald Gutmann, Jochen S. Lau, Marcus Textor, Torsten Barcikowski, Stephan Straube, Thomas |
| Copyright Year | 2017 |
| Abstract | Indium tin oxide (ITO) particle coatings are known for high transparency in the visible, good conductive properties and near-infrared absorption. These properties depend on ITO particle's stoichiometric composition, defects and size. Here we present a method to gradually change ITO particle's optical properties by a simple and controlled laser irradiation process. The defined irradiation process and controlled energy dose input allows one to engineer the absorption and transmission of coatings made from these particles. We investigate the role of the surrounding solvent, influence of laser fluence and the specific energy dose targeting modification of the ITO particle's morphology and chemistry by stepwise laser irradiation in a free liquid jet. TEM, SEM, EDX, XPS, XRD and Raman are used to elucidate the structural, morphological and chemical changes of the laser-induced ITO particles. On the basis of these results the observed modification of the optical properties is tentatively attributed to chemical changes, e.g. laser-induced defects or partial reduction. |
| Starting Page | 6039 |
| Ending Page | 6048 |
| Page Count | 10 |
| File Format | HTM / HTML PDF |
| ISSN | 14779226 |
| Volume Number | 46 |
| Issue Number | 18 |
| Journal | Dalton Transactions |
| DOI | 10.1039/c7dt00010c |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Indium SEM Raman Tin Stoichiometry Laser Solvent Energy density Chemistry Transmission electron microscopy X-ray crystallography |
| Content Type | Text |
| Resource Type | Article |
| Subject | Inorganic Chemistry |
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