NDLI: Synthesis of bimetallic trifluoroacetates through a crystallochemical investigation of their monometallic counterparts: the case of (A, A′)(CF3COO)2·nH2O (A, A′ = Mg, Ca, Sr, Ba, Mn)

Please wait, while we are loading the content...

A series of pure-blue-light emitting Cu(i) complexes with thermally activated delayed fluorescence: structural, photophysical, and computational studies

Synthesis of bimetallic trifluoroacetates through a crystallochemical investigation of their monometallic counterparts: the case of (A, A′)(CF₃COO)₂·nH₂O (A, A′ = Mg, Ca, Sr, Ba, Mn)

Benzene-centered tripodal diglycolamides: synthesis, metal ion extraction, luminescence spectroscopy, and DFT studies

Structural and magnetic properties of semiquinonate based Al(iii) and Ga(iii) complexes

An Ising iron(ii) chain exhibits a large finite-size energy barrier and “hard” magnetic behaviour

Cu(i) and Ag(i) complex formation with the hydrophilic phosphine 1,3,5-triaza-7-phosphadamantane in different ionic media. How to estimate the effect of a complexing medium

Synthesis, reactivity and characterization of Pt(ii) complexes with N,N′ chelating ligands; structure and dimethylsulfoxide reactivity relationship

Multitopic ligand directed assembly of low-dimensional metal-chalcogenide organic frameworks

The W@WO₃ ohmic contact induces a high-efficiency photooxidation performance

Markedly enhanced up-conversion luminescence by combining IR-808 dye sensitization and core–shell–shell structures

Optical properties of trinuclear metal chalcogenolate complexes – room temperature NIR fluorescence in [Cu₂Ti(SPh)₆(PPh₃)₂]

Chiral bidentate [N,S]-ferrocene ligands based on a thiazoline framework. Synthesis and use in palladium-catalyzed asymmetric allylic alkylation

Investigation of a new bis(carboxylate)triazole-based anchoring ligand for dye solar cell chromophore complexes

Highly ordered sandwich-type (phthalocyaninato)(porphyrinato) europium double-decker nanotubes and room temperature NO₂ sensitive properties

Borane-catalyzed indole synthesis through intramolecular hydroamination

Developing the family of picolinate ligands for Mn²⁺ complexation

Cisplatin and valproate released from the bifunctional [Pt^(IV)Cl₂(NH₃)₂(valproato)₂] antitumor prodrug or from liposome formulations: who does what?

The binuclear dual emitter [Br(CO)₃Re(P⋯N)(N⋯P)Re(CO)₃Br] (P⋯N): 3-chloro-6-(4-diphenylphosphinyl)butoxypyridazine, a new bridging P,N-bidentate ligand resulting from the ring opening of tetrahydrofuran

Probing the magnetic relaxation and magnetic moment arrangement in a series of Dy₄ squares

Efficient synthesis of carborane azo derivatives and their reactivity

Trivalent f-elements in human saliva: a comprehensive speciation study by time-resolved laser-induced fluorescence spectroscopy and thermodynamic calculations

Composition-dependent charge transfer and phase separation in the V_1−xRe_xO₂ solid solution

In situ ligand exchange-mediated 0D/1D transformation of a polyoxovanadate

Oxygen vacancy ordering in SrFe_0.25Co_0.75O_2.63 perovskite material

Multi-shelled ceria hollow spheres with a tunable shell number and thickness and their superior catalytic activity

Tridentate Lewis-acids based on triphenylsilane

Photoactive meso-tetra(4-pyridyl)porphyrin-tetrakis-[chloro(2,2′bipyridine)platinum(ii) derivatives recognize and cleave DNA upon irradiation

CO₂ as a hydrogen vector – transition metal diamine catalysts for selective HCOOH dehydrogenation

KB(PO₄)F: a novel acentric deep-ultraviolet material

Synthesis and solution stability of water-soluble κ²N,κO-bis(3,5-dimethylpyrazolyl)ethanol manganese(i) tricarbonyl bromide (CORM-ONN1)

Crystal structure of Ba₂(La_0.727Ba_0.182M_0.091)MO₆ (M = Nb, Sb, Bi): symmetry nuance identified in photoluminescence and IR spectroscopy studies

Using chiral ionic liquid additives to enhance asymmetric induction in a Diels–Alder reaction

Correction: On the mechanism of Ni(ii)-promoted Michael-type hydroamination of acrylonitrile and its substituted derivatives

Back cover

Dalton Transactions Vol - 46 Issue - 4

Dalton Transactions Vol - 46 Issue - 3

Dalton Transactions Vol - 46 Issue - 2

Dalton Transactions Vol -39

Dalton Transactions Vol -0

Synthesis of bimetallic trifluoroacetates through a crystallochemical investigation of their monometallic counterparts: the case of (A, A′)(CF₃COO)₂·nH₂O (A, A′ = Mg, Ca, Sr, Ba, Mn)

Content Provider	Royal Society of Chemistry (RSC)
Author	Mannino, Natalie A. Mendoza, Laura M. Suescun, Leopoldo Dissanayake, K. Tauni Martin, Philip D. Dhanapala, B. Dulani Rabuffetti, Federico A.
Copyright Year	2017
Abstract	Owing to their potential as single-source precursors for compositionally complex materials, there is growing interest in the rational design of multimetallic compounds containing fluorinated ligands. In this work, we show that chemical and structural principles for a materials-by-design approach to bimetallic trifluoroacetates can be established through a systematic investigation of the crystal-chemistry of their monometallic counterparts. A(CF3COO)2·nH2O (A = Mg, Ca, Sr, Ba, Mn) monometallic trifluoroacetates were employed to demonstrate the feasibility of this approach. The crystal-chemistry of monometallic trifluoroacetates was mapped using variable-temperature single-crystal X-ray diffraction, powder X-ray diffraction, and thermal analysis. The evolution with temperature of the previously unknown crystal structure of Mg(CF3COO)2·4H2O was found to be identical to that of Mn(CF3COO)2·4H2O. More important, the flexibility of Mnx(CF3COO)2x·4H2O (x = 1, 3) to adopt two structures, one isostructural to Mg(CF3COO)2·4H2O, the other isostructural to Ca3(CF3COO)6·4H2O, enabled the synthesis of Mg–Mn and Ca–Mn bimetallic trifluoroacetates. Mg0.45Mn0.55(CF3COO)2·4H2O was found to be isostructural to Mg(CF3COO)2·4H2O and exhibited isolated metal–oxygen octahedra with Mg2+ and Mn2+ nearly equally distributed over the metal sites (Mg/Mn: 45/55). Ca1.72Mn1.28(CF3COO)6·4H2O was isostructural to Ca3(CF3COO)6·4H2O and displayed trimers of metal–oxygen corner-sharing octahedra; Ca2+ and Mn2+ were unequally distributed over the central (Ca/Mn: 96/4) and terminal (Ca/Mn: 38/62) octahedral sites.
Starting Page	1420
Ending Page	1430
Page Count	11
File Format	HTM / HTML PDF
ISSN	14779226
Volume Number	46
Issue Number	5
Journal	Dalton Transactions
DOI	10.1039/c6dt04152c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Ba X-ray crystallography Thermal analysis Octahedron
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

La$_{2}$M 3 II Mn$_{4}$O$_{12}$ (M = Mg, Ca, Sr, or Ba) manganites: Synthesis and X-ray diffraction study

Structure of Molten Mg, Ca, Sr, and Ba by X-ray Diffraction

Synthesis and X-ray diffraction study of LaM 1.5 II MnFeO$_{6}$ manganitoferrites (M$^{II}$ = Mg, Ca, Sr, Ba)

Synthesis, structures, and physicochemical properties of Sr$_{2}$A$^{II}$UO$_{6}$ (A$^{II}$ = Mg, Ca, Sr, Ba, Mn, Fe, Co, Ni, Zn, and Cd) compounds

Synthesis and characterization of MTiO3(M = Mg, Ca, Sr, Ba) sol-gel

BDEs of Be(Be+)− Mg(Mg+)− Ca(Ca+)− Sr(Sr+)− Ba(Ba+)−, and Ra−X bonds

Synthesis and X-ray diffraction study of nanostructured particles of cuprate manganites LaM 2 II CuMnO$_{6}$ (M$^{II}$ = Mg, Ca, Sr, Ba)

Synthesis and x-ray diffraction study of new nanostructured manganite ferrites NdM 1.5 II MnFeO$_{6}$ (M$^{II}$ = Mg, Ca, Sr, Ba)

First Principles Investigation of A X A Mg Ca Sr Ba X La Nd Sm Compounds Their Crystal Structures Prediction Electronic and Mechanical Properties

Synthesis of bimetallic trifluoroacetates through a crystallochemical investigation of their monometallic counterparts: the case of (A, A′)(CF₃COO)₂·nH₂O (A, A′ = Mg, Ca, Sr, Ba, Mn)

Similar Documents

La$_{2}$M 3 II Mn$_{4}$O$_{12}$ (M = Mg, Ca, Sr, or Ba) manganites: Synthesis and X-ray diffraction study

Structure of Molten Mg, Ca, Sr, and Ba by X-ray Diffraction

Synthesis and X-ray diffraction study of LaM 1.5 II MnFeO$_{6}$ manganitoferrites (M$^{II}$ = Mg, Ca, Sr, Ba)

Synthesis, structures, and physicochemical properties of Sr$_{2}$A$^{II}$UO$_{6}$ (A$^{II}$ = Mg, Ca, Sr, Ba, Mn, Fe, Co, Ni, Zn, and Cd) compounds

Synthesis and characterization of MTiO3(M = Mg, Ca, Sr, Ba) sol-gel

BDEs of Be(Be+)− Mg(Mg+)− Ca(Ca+)− Sr(Sr+)− Ba(Ba+)−, and Ra−X bonds

Synthesis and X-ray diffraction study of nanostructured particles of cuprate manganites LaM 2 II CuMnO$_{6}$ (M$^{II}$ = Mg, Ca, Sr, Ba)

Synthesis and x-ray diffraction study of new nanostructured manganite ferrites NdM 1.5 II MnFeO$_{6}$ (M$^{II}$ = Mg, Ca, Sr, Ba)

First Principles Investigation of A X A Mg Ca Sr Ba X La Nd Sm Compounds Their Crystal Structures Prediction Electronic and Mechanical Properties

Synthesis of bimetallic trifluoroacetates through a crystallochemical investigation of their monometallic counterparts: the case of (A, A′)(CF3COO)2·nH2O (A, A′ = Mg, Ca, Sr, Ba, Mn)

Synthesis of bimetallic trifluoroacetates through a crystallochemical investigation of their monometallic counterparts: the case of (A, A′)(CF₃COO)₂·nH₂O (A, A′ = Mg, Ca, Sr, Ba, Mn)