NDLI: Ambidentate coordination in hydrogen bonded dimethyl sulfoxide, (CH3)2SO⋯H3O+, and in dichlorobis(dimethyl sulfoxide) palladium(ii) and platinum(ii) solid solvates, by vibrational and sulfur K-edge X-ray absorption spectroscopy

Please wait, while we are loading the content...

Structural characterization and bonding properties of lithium naphthalene radical anion, [Li⁺(TMEDA)₂][C₁₀H₈˙⁻], and lithium naphthalene dianion [(Li⁺TMEDA)₂C₁₀H₈⁻²]

The first continuous silver polyhedra framework containing four kinds of coordination spheres

Joining the crown family; the tetrameric, O-bridged macrocycle [{P(μ-N^tBu)}₂(μ-O)]₄

Selective functionalisation of Re₆ cluster anionic units: from hexa-hydroxo [Re₆Q₈(OH)₆]⁴⁻ (Q = S, Se) to neutral trans-[Re₆Q₈L₄L′₂] hybrid building blocks

Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: first 6⁵·8 CdSO₄-type 3-D framework built by hexa-Cu^II sandwiched polyoxotungstates

Immobilization of ionic liquids in translucent tin dioxide monoliths by sol–gel processing

Synthesis and characterization of redox-active tris(pyrazolyl)borate cobalt complexes

Hydrogenation of imines by phosphonium borate zwitterions: a theoretical study

Ambidentate coordination in hydrogen bonded dimethyl sulfoxide, (CH₃)₂SO⋯H₃O⁺, and in dichlorobis(dimethyl sulfoxide) palladium(ii) and platinum(ii) solid solvates, by vibrational and sulfur K-edge X-ray absorption spectroscopy

Synthetic, structural, photophysical and computational studies of π-conjugated bis- and tris-1,3,2-benzodiazaboroles and related bis(boryl) dithiophenes

Structure and dimensionality of coordination complexes correlated to piperazine conformation: from discrete [Cu^II₂] and [Cu^II₄] complexes to a μ_1,3-N₃⁻ bridged [Cu^II₂]_n chain

Copper(II) Nanoballs as monomers for polyurethane coatings: synthesis, urethane derivatization and kinetic stability

Reactions of cationic transition metal acetonitrile complexes [M(CH₃CN)_n]^m+ with GaCp*: novel gallium complexes of iron, cobalt, copper and silver

Towards a catalytic hydrogenolysis of silicon-silicon bonds: Formation of Si–H bonds from disilanes and H₂ at platinum

Regio- and chemoselective oxidation of the bis(bidentate) phosphine cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphino)cyclobutane via cobalt(II) mediated dioxygen activation

Syntheses, structures and magnetic properties of a family of metal carboxylate polymers viain situ metal–ligand reactions of benzene-1,2,3-tricarboxylic acid

Highly active iridium catalysts for the hydrogenation of ketones and aldehydes

Formation of dimeric and polymeric W/Cu/S clusters via degradation or expansion of the cluster core in [Et₄N]₄[WS₄Cu₄I₆]

[Cu(H₂btec)(bipy)]_∞: a novel metal organic framework (MOF) as heterogeneous catalyst for the oxidation of olefins

Reversible substrate binding at copper centers in neutral copper(i) carbene complexes derived from bis(3-tert-butylimidazole-2-ylidene)methane

Synthesis and characterization of new divalent lanthanide complexes supported by amine bis(phenolate) ligands and their applications in the ring opening polymerization of cyclic esters

Unusual chalcogen-boron ring compounds: the gas-phase structures of 1,4-B₄S₂(NMe₂)₄ and related molecules

DNA oxidation, strand-breaks and etheno-adducts formation promoted by Cu, Zn-superoxide dismutase–H₂O₂ in the presence and absence of bicarbonate

On the interactions of alkyl 2-hydroxycarboxylic acids with alkoxysilanes 2. Complexation and esterification of di- and tricarboxylic acids

Back cover

Dalton Transactions Vol - 0 Issue - 7

Dalton Transactions Vol - 0 Issue - 6

Dalton Transactions Vol - 0 Issue - 5

Ambidentate coordination in hydrogen bonded dimethyl sulfoxide, (CH₃)₂SO⋯H₃O⁺, and in dichlorobis(dimethyl sulfoxide) palladium(ii) and platinum(ii) solid solvates, by vibrational and sulfur K-edge X-ray absorption spectroscopy

Content Provider	Royal Society of Chemistry (RSC)
Author	Risberg, Emiliana Damian Skripkin, Mikhail Yu. Sandström, Magnus Lindqvist-Reis, Patric Bencze, Éva Mink, János Hajba, Laszló Abbasi, Alireza
Copyright Year	2009
Abstract	The strongly hydrogen bonded species (CH3)2SO⋯H3O+ formed in concentrated hydrochloric acid displays a new low energy feature in its sulfur K-edge X-ray absorption near edge structure (XANES) spectrum. Density Functional Theory-Transition Potential (DFT-TP) calculations reveal that the strong hydrogen bonding decreases the energy of the transition S(1s) → LUMO, which has antibonding σ(S–O) character, with about 0.8 eV. Normal coordinate force field analyses of the vibrational spectra show that the SO stretching force constant decreases from 4.72 N cm−1 in neat liquid dimethyl sulfoxide to 3.73 N cm−1 for the hydrogen bonded (CH3)2SO⋯H3O+ species. The effects of sulfur coordination on the ambidentate dimethyl sulfoxide molecule were investigated for the trans-Pd((CH3)2SO)2Cl2, trans-Pd((CD3)2SO)2Cl2 and cis-Pt((CH3)2SO)2Cl2 complexes with square planar coordination of the chlorine and sulfur atoms. The XANES spectra again showed shifts toward low energy for the transition S(1 s) → LUMO, now with antibonding σ(M–Cl, M–S) character, with a larger shift for M = Pt than Pd. DFT-TP calculations indicated that the differences between the XANES spectra of the geometrical cis and trans isomers of the M((CH3)2SO)2Cl2 complexes are expected to be too small to allow experimental distinction. The vibrational spectra of the palladium(II) and platinum(II) complexes were recorded and complete assignments of the fundamentals were achieved. Even though the M–S bond distances are quite similar the high covalency especially of the Pt–S bonds induces significant increases in the S–O stretching force constants, 6.79 and 7.18 N cm−1, respectively.
Starting Page	1328
Ending Page	1338
Page Count	11
File Format	HTM / HTML PDF
ISSN	14779226
Volume Number	0
Issue Number	8
Journal	Dalton Transactions
DOI	10.1039/b814252a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Hydrogen Acid Sulfur K-edge X-ray absorption spectroscopy X-ray absorption near edge structure Antibonding molecular orbital Electronvolt Force field (fiction) Dimethyl sulfoxide Ford CD3 platform Chlorine Chemical bond
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Sulfur k-edge x-ray absorption spectra for dimethyl sulfoxide (2003).

Dimethyl Sulfoxide, (CH3) 2SO

Sulfur K-edge X-ray absorption spectra for dimethyl sulfoxide in the solvated thallium(III), indium(III0, gallium(III) an aluminum(III) ions

(ssrl-m) sulfur and chlorine k-edge x-ray absorption spectroscopic studies of photographic materials (1994).

Chlorine K-Edge X-ray Absorption Spectroscopy as a Probe of Chlorine−Manganese Bonding: Model Systems with Relevance to the Oxygen Evolving Complex in Photosystem II†

X-ray snapshots for metalloporphyrin axial ligation

Layered structure of the near-surface region of oxidized chalcopyrite (CuFeS₂): hard X-ray photoelectron spectroscopy, X-ray absorption spectroscopy and DFT+U studies

XANES investigations and catalytic properties of coprecipitated AlF₃/MgF₂ phases

Exploring reaction dynamics in lithium-sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy.

Ambidentate coordination in hydrogen bonded dimethyl sulfoxide, (CH₃)₂SO⋯H₃O⁺, and in dichlorobis(dimethyl sulfoxide) palladium(ii) and platinum(ii) solid solvates, by vibrational and sulfur K-edge X-ray absorption spectroscopy

Similar Documents

Sulfur k-edge x-ray absorption spectra for dimethyl sulfoxide (2003).

Dimethyl Sulfoxide, (CH3) 2SO

Sulfur K-edge X-ray absorption spectra for dimethyl sulfoxide in the solvated thallium(III), indium(III0, gallium(III) an aluminum(III) ions

(ssrl-m) sulfur and chlorine k-edge x-ray absorption spectroscopic studies of photographic materials (1994).

Chlorine K-Edge X-ray Absorption Spectroscopy as a Probe of Chlorine−Manganese Bonding: Model Systems with Relevance to the Oxygen Evolving Complex in Photosystem II†

X-ray snapshots for metalloporphyrin axial ligation

Layered structure of the near-surface region of oxidized chalcopyrite (CuFeS2): hard X-ray photoelectron spectroscopy, X-ray absorption spectroscopy and DFT+U studies

XANES investigations and catalytic properties of coprecipitated AlF3/MgF2 phases

Exploring reaction dynamics in lithium-sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy.

Ambidentate coordination in hydrogen bonded dimethyl sulfoxide, (CH3)2SO⋯H3O+, and in dichlorobis(dimethyl sulfoxide) palladium(ii) and platinum(ii) solid solvates, by vibrational and sulfur K-edge X-ray absorption spectroscopy

Layered structure of the near-surface region of oxidized chalcopyrite (CuFeS₂): hard X-ray photoelectron spectroscopy, X-ray absorption spectroscopy and DFT+U studies

XANES investigations and catalytic properties of coprecipitated AlF₃/MgF₂ phases

Ambidentate coordination in hydrogen bonded dimethyl sulfoxide, (CH₃)₂SO⋯H₃O⁺, and in dichlorobis(dimethyl sulfoxide) palladium(ii) and platinum(ii) solid solvates, by vibrational and sulfur K-edge X-ray absorption spectroscopy