NDLI: Photooxidation of water by NiTiO3 deposited from single source precursor [Ni2Ti2(OEt)2(μ-OEt)6(acac)4] by AACVD

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Photooxidation of water by NiTiO₃ deposited from single source precursor [Ni₂Ti₂(OEt)₂(μ-OEt)₆(acac)₄] by AACVD

Content Provider	Royal Society of Chemistry (RSC)
Author	Tahir, Asif Ali Mazhar, Muhammad Hamid, Mazhar Wijayantha, K.G. Upul Molloy, Kieran C.
Copyright Year	2009
Abstract	A single-source heterobimetallic complex Ni2Ti2(OEt)2(μ-OEt)6(acac)4 (1) (acac = 2,4-pentanedionate), having a low decomposition temperature and sufficient solubility in organic solvents, was synthesized by simple chemical techniques in high yield and analyzed by melting point, FTIR, single crystal X-ray analysis and thermal analysis. The TGA analysis proved that complex (1) underwent facile thermal decomposition at 500 °C to give NiTiO3 residue. In-house designed aerosol assisted chemical vapor deposition equipment was used to deposit high quality thin films of NiTiO3 on a SnO2 coated conducting glass substrate at 500 °C. An XRD analysis of the thin films proved the formation of crystalline NiTiO3 with average grain size 42 nm. Scanning electron microscopic studies (SEM) show that the thin films consist of flat, plate-like nanoparticles. The current–potential characteristics recorded under AM1.5 illumination indicate that NiTiO3 thin films are anodic and the photocurrent density at 1.23 V vs RHE (Reversible Hydrogen Electrode) is about 40 μA cm−2.
Starting Page	3674
Ending Page	3680
Page Count	7
File Format	HTM / HTML PDF
ISSN	14779226
Volume Number	0
Issue Number	19
Journal	Dalton Transactions
DOI	10.1039/b818765g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	RHE X-ray crystallography Thermal analysis Aerosol Chemical vapor deposition X-ray scattering techniques Scanning electron microscope Air mass (solar energy) Photocurrent
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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Photooxidation of water by NiTiO₃ deposited from single source precursor [Ni₂Ti₂(OEt)₂(μ-OEt)₆(acac)₄] by AACVD