NDLI: Selective aerobic oxidation of activated alkanes with MOFs and their use for epoxidation of olefins with oxygen in a tandem reaction

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Catalysis Science & Technology Vol -2

Catalysis Science & Technology Vol -1

Selective aerobic oxidation of activated alkanes with MOFs and their use for epoxidation of olefins with oxygen in a tandem reaction

Content Provider	Royal Society of Chemistry (RSC)
Author	Luz, I. Corma, A. Boronat, M. Xamena, F. X. Llabrés i León, A.
Copyright Year	2013
Abstract	MOFs with Cu2+ centers linked to four nitrogen atoms from azaheterocyclic compounds, i.e., pyrimidine [Cu(2-pymo)2] and imidazole [Cu(im)2], are active catalysts for aerobic oxidation of activated alkanes, such as tetralin, cumene and ethylbenzene. Differences in activity among the two MOFs appear to be related to differences in their ability to decompose the hydroperoxide and to coordinate to the resulting radical ˙OH species. Copper ions in [Cu(im)2] can coordinate by expanding their coordination sphere from 4 to 5 in a reversible way, while in the case of [Cu(2-pymo)2] it results in a displacement of one of the pyrimidine ligands. The MOFs can be used in combination with a silylated Ti-MCM-41 to catalyze the epoxidation of olefins with oxygen by means of a tandem reaction in which the MOF produces cumene hydroperoxide, which is used by Ti-MCM-41 to epoxidize the olefin.
Starting Page	371
Ending Page	379
Page Count	9
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	3
Issue Number	2
Journal	Catalysis Science & Technology
DOI	10.1039/c2cy20449e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Tetralin Oxygen MOF Silylation Nitrogen Pyrimidine Ethylbenzene Alkene Imidazole Epoxide Cumene Organic peroxide Nucleophile
Content Type	Text
Resource Type	Article
Subject	Catalysis

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