NDLI: Mesostructured graphitic carbon nitride as a new base catalyst for the efficient synthesis of dimethyl carbonate by transesterification

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Mesostructured graphitic carbon nitride as a new base catalyst for the efficient synthesis of dimethyl carbonate by transesterification

Content Provider	Royal Society of Chemistry (RSC)
Author	Xue, Bing Xu, Jie Cao, Yong Chen, Ting Long, Kai-Zhou Li, Yong-Xin
Copyright Year	2013
Abstract	Mesostructured graphitic carbon nitride (CN-MCF) material has been prepared using carbon tetrachloride and ethylenediamine as precursors and mesocellular silica foam as a hard template, and characterized by XRD, N2 adsorption–desorption, TEM, FT-IR, and XPS techniques. The material was employed as a catalyst for the production of dimethyl carbonate (DMC) via transesterification of ethylene carbonate (EC) with methanol (MeOH). The influences of reaction conditions, including time, temperature, and the molar ratios of MeOH to EC, on the catalytic performance have been investigated in detail. Catalytic results revealed that CN-MCF could catalyze the transesterification reaction with high efficiency, affording a high DMC yield of 78% and stable catalytic activity for several running cycles. Furthermore, a possible reaction mechanism for the g-CN-catalyzing transesterification of EC with MeOH has been proposed.
Starting Page	3192
Ending Page	3199
Page Count	8
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	3
Issue Number	12
Journal	Catalysis Science & Technology
DOI	10.1039/c3cy00517h
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Dimethyl carbonate Carbon tetrachloride Ethylene carbonate Fourier-transform infrared spectroscopy Transesterification Concentration Silicon dioxide Graphitic carbon nitride X-ray crystallography Ethylenediamine Transmission electron microscopy Reaction mechanism Nitride EC Methanol
Content Type	Text
Resource Type	Article
Subject	Catalysis

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