NDLI: Gold, palladium and gold–palladium supported nanoparticles for the synthesis of glycerol carbonate from glycerol and urea

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Versatility of heterogeneous photocatalysis: synthetic methodologies epitomizing the role of silica support in TiO₂ based mixed oxides

Enzymatic synthesis of sugar fatty acid esters in ionic liquids

Diesel fuel from biomass

Alloys in catalysis: phase separation and surface segregation phenomena in response to the reactive environment

Selective photocatalytic oxidation of gaseous ammonia to dinitrogen in a continuous flow reactor

Deactivation mechanism of potassium additives on Ti_0.8Zr_0.2Ce_0.2O_2.4 for NH₃-SCR of NO

An in situ spatially resolved method to probe gas phase reactions through a fixed bed catalyst

Catalytic decoloration of methyl orange solution by nanoporous metals

Gold(iii)–oxo complexes as catalysts in intramolecular hydroamination

Identification of active oxygen species for soot combustion on LaMnO₃ perovskite

Template-free synthesis of ternary sulfides submicrospheres as visible light photocatalysts by ultrasonic spray pyrolysis

Efficient microwave-assisted production of furfural from C₅ sugars in aqueous media catalysed by Brönsted acidic ionic liquids

Highly active Cu/MgO catalysts for selective dehydrogenation of benzyl alcohol into benzaldehyde using neither O₂ nor H₂ acceptor

Increased hydrolysis by Thermomyces lanuginosus lipase for omega-3 fatty acids in the presence of a protic ionic liquid

Transesterifications using a hydrocalumite synthesized from waste slag: an economical and ecological route for biofuel production

Conversion of cellulose to polyols over promoted nickel catalysts

A recyclable magnetic nanoparticles supported palladium catalyst for the Hiyama reaction of aryltrialkoxysilanes with aryl halides

Promotional role of ceria on cobaltosic oxide catalyst for low-temperature CO oxidation

Cu/AlO(OH)-catalyzed formation of β-enamino ketones/esters under solvent, ligand and base free conditions – experimental and computational studies

Homogenization of inorganic material-supported palladium catalysts in Suzuki coupling reaction at room temperature

Palladium complexes grafted onto mesoporous silica catalysed the double carbonylation of aryl iodides with amines to give α-ketoamides

Synthesis, characterization and catalytic performance of Mo-TUD-1 catalysts in epoxidation of cyclohexene

Hydrogenation of geraniol using ruthenium–BINAP catalysts

Influence of reaction conditions on the direct synthesis of hydrogen peroxide over AuPd/carbon catalysts

Gold, palladium and gold–palladium supported nanoparticles for the synthesis of glycerol carbonate from glycerol and urea

Co-promotion of fluorine and boron on NiMo/Al₂O₃ for hydrotreating light cycle oil

Hierarchical TiO₂ spherical nanostructures with tunable pore size, pore volume, and specific surface area: facile preparation and high-photocatalytic performance

A rapid and eco-friendly synthesis of novel and known benzopyrazines using silica tungstic acid (STA) as a new and recyclable catalyst

Visible light photochemical activity of heterostructured PbTiO₃–TiO₂ core–shell particles

Preparation of hierarchical dandelion-like CuO microspheres with enhanced catalytic performance for dimethyldichlorosilane synthesis

Morphology of active species of Ag/ZrO₂ for low-temperature soot oxidation by oxygen

Catalytic hydrogenolysis of biodiesel derived glycerol to 1,2-propanediol over Cu–MgO catalysts

A heterogeneous Co₃O₄–Bi₂O₃ composite catalyst for oxidative degradation of organic pollutants in the presence of peroxymonosulfate

Insight into the catalytic mechanism of glycerol hydrogenolysis using basal spacing of hydrotalcite as a tool

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Catalysis Science & Technology Vol -1

Gold, palladium and gold–palladium supported nanoparticles for the synthesis of glycerol carbonate from glycerol and urea

Content Provider	Royal Society of Chemistry (RSC)
Author	Kiely, Christopher J. Carley, Albert F. Hammond, Ceri Rahim, Mohd Hasbi Ab Dimitratos, Nikolaos He, Qian Sankar, Meenakshisundaram Knight, David W. Hutchings, Graham J. Lopez-Sanchez, Jose A.
Copyright Year	2012
Abstract	Supported Au–Pd nanoparticles are shown to be effective catalysts for the transformation of glycerol into glycerol carbonate. The reaction of glycerol with urea to form glycerol carbonate is a very attractive reaction that utilises two inexpensive and readily available raw materials in a chemical cycle that, overall, results in the chemical fixation of carbon dioxide. Previous reports are largely based on the utilisation of high concentrations of metal sulphates or oxides, which suffer from low intrinsic activity and selectivity and limited recoverability due to the dissolution of the catalyst in the reaction media. We now report that magnesium oxide is an excellent support for gold and bimetallic gold–palladium nanoparticles for this reaction. The preparation method and pre-treatment affect the catalytic performance and a colloidal preparation route produces the most active catalysts.
Starting Page	1914
Ending Page	1924
Page Count	11
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	2
Issue Number	9
Journal	Catalysis Science & Technology
DOI	10.1039/c2cy20288c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Urea Magnesium oxide Carbon dioxide Glycerol Serializability Intrinsic activity
Content Type	Text
Resource Type	Article
Subject	Catalysis

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The Role of Tungsten Oxide Species Supported on Titania Catalysts for the Synthesis of Glycerol Carbonate from Glycerol and Urea

Catalytic performance of polymer-supported ionic liquids in the synthesis of glycerol carbonate from glycerol and urea

Direct synthesis of glycerol carbonate from glycerol and carbon dioxide by Brønsted base catalysis

Nanocrystalline magnesium oxide-stabilized palladium(0): an efficient and reusable catalyst for synthesis of N-(2-pyridyl)indoles

Synthesis of glycerol carbonate from glycerol and urea with gold-based catalysts

The Synthesis of Glycerol Carbonate from Glycerol and Carbon Dioxide over Supported CuO-Based Nanoparticle Catalyst.

One-Pot Synthesis of Dimethyl Carbonate from Methanol, Propylene Oxide and Carbon Dioxide Over Supported Choline hydroxide/MgO

Lanthanum-based mixed oxides for the synthesis of glycerol carbonate from glycerol and urea

Synthesis of glycerol carbonate from glycerol and urea with gold-based catalysts

Gold, palladium and gold–palladium supported nanoparticles for the synthesis of glycerol carbonate from glycerol and urea

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The Role of Tungsten Oxide Species Supported on Titania Catalysts for the Synthesis of Glycerol Carbonate from Glycerol and Urea

Catalytic performance of polymer-supported ionic liquids in the synthesis of glycerol carbonate from glycerol and urea

Direct synthesis of glycerol carbonate from glycerol and carbon dioxide by Brønsted base catalysis

Nanocrystalline magnesium oxide-stabilized palladium(0): an efficient and reusable catalyst for synthesis of N-(2-pyridyl)indoles

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