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POM@IL-MOFs – inclusion of POMs in ionic liquid modified MOFs to produce recyclable oxidation catalysts

Content Provider	Royal Society of Chemistry (RSC)
Author	Leus, Karen Derakhshandeh, Parviz Gohari Nahra, Fady Driessche, Isabel Van Hecke, Kristof Van Voort, Pascal Van Der Abbasi, Alireza Abednatanzi, Sara Keukeleere, Katrien De Nolan, Steven P.
Copyright Year	2017
Abstract	In this study, we present for the first time the immobilization of phosphotungstic acid (H3PW12O40, HPW) into the nanocages of a dual amino-functionalized ionic liquid (DAIL)-modified MIL-101(Cr) framework under mild conditions. The obtained PW/DAIL/MIL-101(Cr) was evaluated as a catalyst in the oxidation of benzyl alcohol using TBHP in chloroform. In order to obtain insights into the role of the DAIL during catalysis, a DAIL-free catalyst (HPW/MIL-101(Cr)) was also prepared. Both catalysts were fully characterized using several techniques. In comparison with the HPW/MIL-101(Cr) material, PW/DAIL/MIL-101(Cr) showed an enhanced catalytic performance in the selective oxidation of benzyl alcohol. This was mainly attributed to the ability of the DAIL groups to form hydrogen bonds, thus enhancing the accessibility of TBHP. Furthermore, the immobilization of the DAIL groups onto MIL-101(Cr) resulted in increased thermal stability of the obtained PW/DAIL/MIL-101(Cr) which showed stability up to 400 °C. Moreover, the PW/DAIL/MIL-101(Cr) catalyst exhibited good recyclability and selectivity. The catalyst could be reused for at least five cycles with no significant leaching of the tungsten species or loss of crystallinity and activity.
Starting Page	1478
Ending Page	1487
Page Count	10
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	7
Issue Number	7
Journal	Catalysis Science & Technology
DOI	10.1039/c6cy02662a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Acid Gold nanocage Chloroform Tungsten Benzyl alcohol DAIL Ionic liquid Hydrogen bond
Content Type	Text
Resource Type	Article
Subject	Catalysis

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POM@IL-MOFs – inclusion of POMs in ionic liquid modified MOFs to produce recyclable oxidation catalysts

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