NDLI: Preparation of KF–La2O2CO3 solid base catalysts and their excellent catalytic activities for transesterification of tributyrin with methanol

Content Provider	Royal Society of Chemistry (RSC)
Author	Niu, Xiaoyu Fu, Honggang Jiang, Wen Yuan, Fulong Zhu, Yujun
Copyright Year	2014
Abstract	A series of 25% KF–La2O2CO3 catalysts (25-KF–LOC-x, x = 673, 723 and 773) were prepared at different calcination temperatures, which were tested as basic catalysts for the transesterification of tributyrin with methanol to produce methyl butyrate and characterized by means of XRD, SEM, CO2-TPD, FTIR, XPS and XRF. It was found that the calcination temperature greatly influences the catalytic activity, and its order is 25-KF–LOC-673 < 25-KF–LOC-723 < 25-KF–LOC-773. Especially, the 25-KF–LOC-773 catalyst exhibits a very high activity, and the conversion of tributyrin is nearly 100%, the yield of methyl butyrate reaches 94% at 308 K. The activation energy of the 25-KF–LOC-773 catalyst is as low as 55.03 kJ mol−1. The excellent catalytic activity of the 25-KF–LOC-773 catalyst can be attributed to the largest amount of surface hydroxyl among these 25-KF–LOC-x catalysts. The results indicate that the Brønsted base is the main active site at low reaction temperature. The recycling use and stability have been investigated over the 25-KF–LOC-773 catalyst. The results indicate that the 25-KF–LOC-773 catalyst has a high stability after being stored for 90 days. The deactivation of the used 25-KF–LOC-773 catalyst at 308 K is due to the loss of hydroxyl on the surface. However, the conversion of tributyrin can reach 91%, and the yield of methyl butyrate also can achieve 64% when the transesterification reaction is performed at 338 K over the second used 25-KF–LOC-773 catalyst. It indicates that the second used 25-KF–LOC-773 catalyst still possesses good catalytic activity at the higher reaction temperature due to the unchanged strong Lewis basic sites provided with surface oxygen anions.
Starting Page	2957
Ending Page	2968
Page Count	12
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	4
Issue Number	9
Journal	Catalysis Science & Technology
DOI	10.1039/c4cy00167b
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Active site Tributyrin Calcination Transesterification 90 Days (film) X-ray crystallography Methyl butyrate Hydroxy group X-ray fluorescence Lewis SEM Activation energy Methanol Nucleophile
Content Type	Text
Resource Type	Article
Subject	Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Activity and stability of solid base KF/La$_{2}$O$_{3}$ catalysts for transesterification of tributyrin with methanol

Catalytic performance and mechanism of KF-loaded catalysts for biodiesel synthesis

Preparation and activity of Cu/Zn/Al/Zr catalysts via hydrotalcite-containing precursors for methanol synthesis from CO₂ hydrogenation

Pillared clays as catalysts for methyl parathion removal by advanced oxidation processes

A facile, low-cost route for the preparation of calcined porous calcite and dolomite and their application as heterogeneous catalysts in biodiesel production

Preparation of highly dispersed catalytic Cu from rod-like CuO–CeO₂ mixed metal oxides: suitable for applications in high performance methanol steam reforming

Transesterification of glycerol with dimethyl carbonate for the synthesis of glycerol carbonate over Mg/Zr/Sr mixed oxide base catalysts

La-modified mesoporous Mg–Al mixed oxides: effective and stable base catalysts for the synthesis of dimethyl carbonate from methyl carbamate and methanol

Selective ortho butylation of phenol over sulfated Fe₂O₃–TiO₂

Preparation of KF–La₂O₂CO₃ solid base catalysts and their excellent catalytic activities for transesterification of tributyrin with methanol

Similar Documents

Activity and stability of solid base KF/La$_{2}$O$_{3}$ catalysts for transesterification of tributyrin with methanol

Catalytic performance and mechanism of KF-loaded catalysts for biodiesel synthesis

Preparation and activity of Cu/Zn/Al/Zr catalysts via hydrotalcite-containing precursors for methanol synthesis from CO2 hydrogenation

Pillared clays as catalysts for methyl parathion removal by advanced oxidation processes

A facile, low-cost route for the preparation of calcined porous calcite and dolomite and their application as heterogeneous catalysts in biodiesel production

Preparation of highly dispersed catalytic Cu from rod-like CuO–CeO2 mixed metal oxides: suitable for applications in high performance methanol steam reforming

Transesterification of glycerol with dimethyl carbonate for the synthesis of glycerol carbonate over Mg/Zr/Sr mixed oxide base catalysts

La-modified mesoporous Mg–Al mixed oxides: effective and stable base catalysts for the synthesis of dimethyl carbonate from methyl carbamate and methanol

Selective ortho butylation of phenol over sulfated Fe2O3–TiO2

Preparation of KF–La2O2CO3 solid base catalysts and their excellent catalytic activities for transesterification of tributyrin with methanol

Preparation and activity of Cu/Zn/Al/Zr catalysts via hydrotalcite-containing precursors for methanol synthesis from CO₂ hydrogenation

Preparation of highly dispersed catalytic Cu from rod-like CuO–CeO₂ mixed metal oxides: suitable for applications in high performance methanol steam reforming

Selective ortho butylation of phenol over sulfated Fe₂O₃–TiO₂

Preparation of KF–La₂O₂CO₃ solid base catalysts and their excellent catalytic activities for transesterification of tributyrin with methanol