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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Yu, Yunbo He, Hong Deng, Hua Zhang, Xiuli |
| Copyright Year | 2014 |
| Abstract | CH4, C2H2, C2H4, C3H6, and C3H8 were selected as reductants for selective catalytic reduction (SCR) of NOx over Ag/Al2O3. Activity measurement showed that NOx reduction by hydrocarbons containing two- or three-carbon atoms was clearly promoted by H2 over Ag/Al2O3 at low temperatures, while such enhancement did not occur in the case of CH4-SCR. Gas chromatography and gas chromatography coupled to a mass spectrometer analysis showed that the partial oxidation of hydrocarbons with more than one carbon atom was triggered at low temperatures by H2 addition over Ag/Al2O3. On the surface of Ag/Al2O3, in situ diffuse reflectance infrared Fourier transform spectra indicated that this enhancement mainly originated from the formation of reactive enolic species, which is a common feature of H2-assisted HC-SCR. |
| Starting Page | 1239 |
| Ending Page | 1245 |
| Page Count | 7 |
| File Format | HTM / HTML PDF |
| ISSN | 20444753 |
| Volume Number | 4 |
| Issue Number | 5 |
| Journal | Catalysis Science & Technology |
| DOI | 10.1039/c3cy01033c |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Gas chromatography Fourier Diffuse reflectance infrared fourier transform NOx Selective catalytic reduction Mass spectrometry Carbon |
| Content Type | Text |
| Resource Type | Article |
| Subject | Catalysis |
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