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Catalysis Science & Technology Vol - 4 Issue - 3

Catalysis Science & Technology Vol - 4 Issue - 2

Catalysis Science & Technology Vol -3

Catalysis Science & Technology Vol -2

Catalysis Science & Technology Vol -1

Thin film formation of Pd/reduced-graphene oxide and Pd nanoparticles at oil–water interface, suitable as effective catalyst for Suzuki–Miyaura reaction in water

Content Provider	Royal Society of Chemistry (RSC)
Author	Hoseini, S. Jafar Nasrabadi, Hasan Dehghani, Modarres
Copyright Year	2014
Abstract	A facile and efficient route was used to synthesise Pd nanoparticles by reduction of an organopalladium(II) complex, [PdCl2(cod)] (cod = cis,cis-1,5-cyclooctadiene), at the oil–water interface. Pd/reduced-graphene oxide and Pd free stabilizer nanoparticle thin films were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction and transmission electron microscopy (TEM). Our study shows that both of these nanoparticles were suitable for the Suzuki–Miyaura carbon–carbon coupling reaction. Compared to the classical reactions, this method consistently has the advantages of a green solvent, short reaction times, low catalyst loading, high yields and reusability of the catalyst. Furthermore, Pd nanoparticles show a high catalytic activity toward aryl chloride derivatives.
Starting Page	1078
Ending Page	1083
Page Count	6
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	4
Issue Number	4
Journal	Catalysis Science & Technology
DOI	10.1039/c3cy01068f
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Miyaura Nanoparticle Fourier-transform infrared spectroscopy X-ray crystallography Transmission electron microscopy Fourier Classical mechanics Aryl halide 1,5-Cyclooctadiene Suzuki Green chemistry Organopalladium Coupling reaction
Content Type	Text
Resource Type	Article
Subject	Catalysis

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