NDLI: Dynamic spin interchange in a tridentate Fe(iii) Schiff-base compound

Content Provider	Royal Society of Chemistry (RSC)
Author	Vicente, Ana I. Rodrigues, Vítor H. N. Martinho, Paulo N. Diogo, Hermínio P. Carvalho, Maria de Deus Calhorda, Maria José Duttine, Mathieu Piedade, Manuel E. Minas da Ferreira, Liliana P. Joseph, Abhinav
Copyright Year	2016
Abstract	The thermosalient effect is still a rare and poorly understood phenomenon, where crystals suddenly jump, bend, twist or explode upon undergoing a thermally activated phase transition. The synthesis and characterisation of the new spin transition Fe(III) compound [Fe(5-Br-salEen)2][ClO4] (salEen = N-ethyl-N-(2-aminoethyl)salicylaldiminate) is described and its thermosalient behaviour reported. It is the first example of a thermosalient effect with a spin transition and magnetic, calorimetric, diffraction, microscopy and computational studies are used to characterise these effects. Both thermosalient effect and spin transition occur around 320 K upon heating and are accompanied by an anisotropic unit cell change with conservation of crystal symmetry that causes a large enough stress of the crystal lattice to induce crystal explosion. This stress can ultimately be traced back to a diffusionless and distortive structural perturbation resulting in a coupled spin transition-thermosalient effect.
Starting Page	4251
Ending Page	4258
Page Count	8
File Format	HTM / HTML PDF
ISSN	20416520
Volume Number	7
Issue Number	7
Journal	Chemical Science
DOI	10.1039/c5sc04577k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	Spin transition Microscopy Anisotropy Phase transition Crystal structure
Content Type	Text
Resource Type	Article
Subject	Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis and Crystal Structure of N-(2-Pyridylmethyl)-L-Alanine) Isothiocyanate Cobalt(III)

A Series of Molybdenum(VI) Complexes with Tridentate Schiff Base Ligands

Synthesis, Antibacterial Studies and Crystal Structures of Tridentate Schiff Base Ligand and It’s Cobalt(III) Complex

A Mn(III) single ion magnet with tridentate Schiff-base ligands

Syntheses, Crystal Structures, and Antibacterial Activity of New Tetranuclear Zinc(II) Complexes with Schiff Base Ligands

A Chiral Tridentate Schiff Base Catalyst for Alkylzinc Addition to Aldehydes

A Pair of Manganese(III) Schiff-Base Enantiomers: Synthesis, Crystal Structure and Magnetic Characterization

Synthesis, Crystal Structures and Catalytic Property of Dioxomolybdenum(VI) Complexes Derived from Tridentate Schiff Bases

Synthesis, Antibacterial Studies and Crystal Structures of Tridentate Schiff Base Ligand and It’s Cobalt(III) Complex

Dynamic spin interchange in a tridentate Fe(iii) Schiff-base compound

Similar Documents

Synthesis and Crystal Structure of N-(2-Pyridylmethyl)-L-Alanine) Isothiocyanate Cobalt(III)

A Series of Molybdenum(VI) Complexes with Tridentate Schiff Base Ligands

Synthesis, Antibacterial Studies and Crystal Structures of Tridentate Schiff Base Ligand and It’s Cobalt(III) Complex

A Mn(III) single ion magnet with tridentate Schiff-base ligands

Syntheses, Crystal Structures, and Antibacterial Activity of New Tetranuclear Zinc(II) Complexes with Schiff Base Ligands

A Chiral Tridentate Schiff Base Catalyst for Alkylzinc Addition to Aldehydes

A Pair of Manganese(III) Schiff-Base Enantiomers: Synthesis, Crystal Structure and Magnetic Characterization

Synthesis, Crystal Structures and Catalytic Property of Dioxomolybdenum(VI) Complexes Derived from Tridentate Schiff Bases

Synthesis, Antibacterial Studies and Crystal Structures of Tridentate Schiff Base Ligand and It’s Cobalt(III) Complex

Dynamic spin interchange in a tridentate Fe(iii) Schiff-base compound