NDLI: Versatile rare earth hexanuclear clusters for the design and synthesis of highly-connected <b>ftw</b>-MOFs

Content Provider	Royal Society of Chemistry (RSC)
Author	Alkordi, Mohamed Norton, George Weseliński, Łukasz J. Eddaoudi, Mohamed Cairns, Amy J. Luebke, Ryan Belmabkhout, Youssef Wojtas, Łukasz Adil, Karim
Copyright Year	2015
Abstract	A series of highly porous MOFs were deliberately targeted to contain a 12-connected rare earth hexanuclear cluster and quadrangular tetracarboxylate ligands. The resultant MOFs have an underlying topology of ftw, and are thus (4,12)-c ftw-MOFs. This targeted rare earth ftw-MOF platform offers the potential to assess the effect of pore functionality and size, via ligand functionalization and/or expansion, on the adsorption properties of relevant gases. Examination of the gas adsorption properties of these compounds showed that the ftw-MOF-2 analogues, constructed from rigid ligands with a phenyl, naphthyl, or anthracene core exhibited a relatively high degree of porosity. The specific surface areas and pore volumes of these analogs are amongst the highest reported for RE-based MOFs. Further studies revealed that the Y-ftw-MOF-2 shows promise as a storage medium for methane (CH4) at high pressures. Furthermore, Y-ftw-MOF-2 shows potential as a separation agent for the selective removal of normal butane (n-C4H10) and propane (C3H8) from natural gas (NG) as well as interesting properties for the selective separation of n-C4H10 from C3H8 or isobutane (iso-C4H10).
Starting Page	4095
Ending Page	4102
Page Count	8
File Format	HTM / HTML PDF
ISSN	20416520
Volume Number	6
Issue Number	7
Journal	Chemical Science
DOI	10.1039/c5sc00614g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	Methane Butane Anthracene Adsorption Ligand Topology Phenyl group Porosity Isobutane Propane Natural gas
Content Type	Text
Resource Type	Article
Subject	Chemistry

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hexanuclear clusters for the design and synthesis of highly-connected ftw-MOFs †

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