NDLI: Metal–organic coordination architectures of 9,10-bis(N-benzimidazolyl)anthracene: syntheses, structures and emission properties

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Metal–organic coordination architectures of 9,10-bis(N-benzimidazolyl)anthracene: syntheses, structures and emission properties

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CrystEngComm Vol - 9 Issue - 4

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CrystEngComm Vol - 9 Issue - 2

Metal–organic coordination architectures of 9,10-bis(N-benzimidazolyl)anthracene: syntheses, structures and emission properties

Content Provider	Royal Society of Chemistry (RSC)
Author	Hu, Tong-Liang Li, Jian-Rong Wang, Duo-Zhi Zeng, Yong-Fei Li, Lei Bu, Xian-He
Copyright Year	2007
Abstract	In our continuing efforts to investigate functional metal-organic coordination architectures, a benzimidazole-based rigid ligand, 9,10-bis(N-benzimidazolyl)anthracene (L), has been designed and used to react with CuI, AgI, CdII, MnII salts, giving rise to five new metal-organic coordination architectures, [CuLI]2·2CHCl3·H2O (1), [CdL2(NO3)2]·4C2H5OH (2), [AgL(BF4)]·3CHCl3 (3), [AgL(NO3)]·2CHCl3 (4) and [MnL2Cl2]·2CHCl3 (5), which were characterized by elemental analyses, IR spectroscopy, and X-ray crystallography. In 1, the CuI ion takes tetrahedral coordination geometry, and the rigid ligands bridge two dinuclear [Cu2I2] units to form a two-dimensional (2-D) layer. 2 and 5 show 2-D network structure with (4,4) topology in which the metal ions have octahedral coordination geometry. 3 and 4 display one-dimensional (1-D) chain structures, but show different crystal packing modes due to the effect of anions. These results indicate that the nature of ligand, metal coordination geometry and counter-anions have important effects on the structural topologies of such complexes. Furthermore, complexes 1–4 display strong blue emissions in solid state at room temperature.
Starting Page	412
Ending Page	420
Page Count	9
File Format	HTM / HTML PDF
ISSN	14668033
Volume Number	9
Issue Number	5
Journal	CrystEngComm
DOI	10.1039/b701551h
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	X-ray crystallography Infrared spectroscopy Anthracene Ligand Metalorganics Elemental analysis Octahedral molecular geometry Ion Topology Water of crystallization Molecular geometry
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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