NDLI: Investigation of the phase behaviour of the 1 : 1 adduct of mesitylene and hexafluorobenzene

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CrystEngComm Vol - 19 Issue - 6

CrystEngComm Vol - 19 Issue - 5

CrystEngComm Vol - 19 Issue - 4

CrystEngComm Vol - 19 Issue - 3

CrystEngComm Vol - 19 Issue - 2

Investigation of the phase behaviour of the 1 : 1 adduct of mesitylene and hexafluorobenzene

Content Provider	Royal Society of Chemistry (RSC)
Author	Shephard, Jacob J. Singh, Anjali Ghosh, Ronen E. Williams, Jeffrey H. Cockcroft, Jeremy K.
Copyright Year	2017
Abstract	Variable temperature X-ray diffraction has been used to probe the structure and dynamics of the solid adducts of 1,3,5-trimethylbenzene (mesitylene) and hexafluorobenzene. PXRD patterns and DSC traces of near equimolar mixtures reveal two solid-state phase-transitions at 179.2 K and 111.0 K. The crystal structures of all three solid phases of this material have been solved by SXD. In contrast to previous studies on the adduct benzene–hexafluorobenzene, there is pairing of the mesitylene and hexafluorobenzene molecules in all three phases, each consisting of close-packed parallel columns of alternating C6H3(CH3)3 and C6F6 molecules packed face to face in a staggered conformation. Differences in structure between the phases illustrate the subtle interplay of quadrupole versus bond-dipole electrostatic interactions.
Starting Page	1019
Ending Page	1023
Page Count	5
File Format	HTM / HTML PDF
ISSN	14668033
Volume Number	19
Issue Number	7
Journal	CrystEngComm
DOI	10.1039/c6ce02581a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	X-ray crystallography Quadrupole Trimethylbenzenes Hexafluorobenzene DSC Interplay Entertainment Mesitylene Staggered conformation Adduct
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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