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Annual Reports Section "B" (Organic Chemistry) Vol -109

Annual Reports Section "B" (Organic Chemistry) Vol -99

1 Introduction ( Annual Reports Section "B" (Organic Chemistry) Vol -99 )

2 Synthetic methodsPart (i) Free-radical reactions

2 Synthetic methodsPart (ii) Oxidation and reduction methods

2 Synthetic methodsPart (iii) Biocatalysis and enzymes in organic synthesis

2 Synthetic methodsPart (iv) Heteroatom methods

2 Synthetic methodsPart (v) Protecting groups

3 Transition metals in organic synthesisPart (i) Catalytic applications

3 Transition metals in organic synthesisPart (ii) Stoichiometric applications

4 Heterocyclic chemistry

5 Marine natural products

6 Total synthesis highlights

7 Supramolecular chemistry

8 Natural polymers—chemistry

9 Computational organic chemistry

10 Reaction mechanismsPart (i) Radical and radical ion reactions

10 Reaction mechanismsPart (ii) Polar reactions

10 Reaction mechanismsPart (iii) Pericyclic reactions

11 Organic photochemistry

12 Organic gas-phase ion chemistry

13 Bioinspired organic chemistry

Annual Reports Section "B" (Organic Chemistry) Vol -89

Annual Reports Section "B" (Organic Chemistry) Vol -79

Annual Reports Section "B" (Organic Chemistry) Vol -69

3 Transition metals in organic synthesisPart (i) Catalytic applications

Content Provider	Royal Society of Chemistry (RSC)
Author	Fairlamb, Ian. J. S.
Copyright Year	2003
Abstract	Important investigations in many key areas have been reported upon in 2002. Transition metal catalysed reactions continue to grow in stature, with outstanding selectivity and high yields observed in both old and new synthetic transformations. In particular, a number of efficient ruthenium catalysts have been developed for the cross-metathesis of alkenes, making this a very useful synthetic transformation. Efficient palladium-catalysts for carbon–carbon and carbon–heteroatom bond forming processes continue to be developed, with more catalysts able to transform the less reactive aryl chlorides in a variety of cross-coupling reactions. The versatility of the ruthenium-catalysed cycloisomerisation reactions of 1,n-enynes (n = 6 or 7) is a worthy contribution, which facilitates the synthesis of a range of carbo- and hetero-cycles with excellent regio- and stereo-selectivities. A significant advance in the asymmetric molybdenum-catalysed allylic substitution reaction has been achieved. This reaction is highly regio- and enantio-selective, and for unsymmetrical allylic substrates competes with the palladium-catalysed variant. The review contains a selection of transition metal catalysed reactions from the chemical literature of 2002. Some reactions also involve a stoichiometric metal component in addition to the transition metal catalyst. The review is divided into reaction type. The review is written in the style of previous years.
Starting Page	104
Ending Page	137
Page Count	34
File Format	HTM / HTML PDF
ISSN	00693030
Volume Number	99
Journal	Annual Reports Section "B" (Organic Chemistry)
DOI	10.1039/b212001c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Stoichiometry Ruthenium Chemical bond Allylic rearrangement Transition metal Aryl Olefin metathesis
Content Type	Text
Resource Type	Article
Subject	Chemistry

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3 Transition metals in organic synthesisPart (ii) Stoichiometric applications

Chapter 1: introduction to olefin metathesis.

Cyclic (Alkyl)(amino)carbenes (CAACs) in Ruthenium Olefin Metathesis

Chelating Ruthenium Phenolate Complexes: Synthesis, General Catalytic Activity, and Applications in Olefin Metathesis Polymerization

Olefin Metathesis Catalyzed by a Ruthenium Complex Immobilized on a Chromium–Organic Framework

ESIMS Studies and Calculations on Alkali-Metal Adduct Ions of Ruthenium Olefin Metathesis Catalysts and Their Catalytic Activity in Metathesis Reactions

Olefin Metathesis with Metal–Organic Framework Adsorbed Ruthenium Complexes

Recent applications of ring-rearrangement metathesis in organic synthesis

Light-Mediated Ruthenium-Catalyzed Olefin Metathesis

3 Transition metals in organic synthesisPart (i) Catalytic applications

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3 Transition metals in organic synthesisPart (i) Catalytic applications