NDLI: Fast chemical fingerprinting analysis for biodiesel/diesel blends using commercial solid phase extraction (SPE) cartridge and gas chromatography–mass spectrometry (GC

Please wait, while we are loading the content...

Potential of solid sampling high-resolution continuum source graphite furnace atomic absorption spectrometry to monitor the Ag body burden in individual Daphnia magna specimens exposed to Ag nanoparticles

Self-powered herbicide biosensor utilizing thylakoid membranes

Notes on the use of Mandel's test to check for nonlinearity in laboratory calibrations

On-site solid phase extraction and HPLC determination of chloramphenicol in surface water and sewage

Quantification of multiple bile acids in uninephrectomized rats using ultra-performance liquid chromatography-tandem mass spectrometry

Automated dynamic headspace followed by a comprehensive two-dimensional gas chromatography full scan time-of-flight mass spectrometry method for screening of volatile organic compounds (VOCs) in water

Validation of an analytical method for the refractive index measurement of glass fragments. Application to a hit-and-run incident

Improved hollow fiber supported liquid–liquid–liquid membrane microextraction for speciation of inorganic and organic mercury by capillary electrophoresis

Optimization and validation of a new pesticide residue method for cucumber and tomato using acetonitrile-based extraction-dispersive liquid–liquid microextraction followed by liquid chromatography-tandem mass spectrometry

New redox and conducting polymer modified electrodes for cholesterol biosensing

Fast chemical fingerprinting analysis for biodiesel/diesel blends using commercial solid phase extraction (SPE) cartridge and gas chromatography–mass spectrometry (GC–MS)

Using electrochemistry for metabolite simulation and synthesis in preventive doping research: application to the Rycal S107 and the PPARδ-agonist GW1516

An ultra performance liquid chromatography-electrospray ionization-mass spectrometry method for the rapid analysis of nitrate in drinking water

Modular pressurized liquid extraction for simultaneous extraction, clean-up and fractionation of PCDD/Fs in soil, sediment and sludge samples

Micellar electrokinetic capillary chromatographic determination of a polypill combination containing, lisinopril, hydrochlorothiazide, aspirin, and atorvastatin

Functional monomer free synthesis of molecularly imprinted titania for solid-phase extraction of nicotinic acid

l-Ascorbic acid biosensing assay from enzyme-immobilized pig bladder membrane as a novel platform

Analysis of the aroma components in tobacco using combined GC-MS and AMDIS

Elaidic acid, vaccenic acid and rumenic acid (c9,t11-CLA) determination in human plasma phospholipids and human milk by fast gas chromatography

Indium tin oxide electrode modified by a SH⁺ ion implantation technique for direct electrocatalytic sensing of hydrogen peroxide

A novel capillary electrophoresis-based assay method for coenzyme B₆-dependent diaminopimelate decarboxylase from Propionibacterium acnes

Simultaneous determination of metronidazole, chloramphenicol and 10 sulfonamide residues in honey by LC–MS/MS

Rapid and sensitive determination of acrylamide in potato crisps using reversed-phase direct immersion single drop microextraction-gas chromatography

Analysis of trace elements in complex matrices (soil) by Laser Induced Breakdown Spectroscopy (LIBS)

Validated voltammetric determination of olmesartan medoxomil: Method development and electrochemical behaviors investigation

An eco-friendly hydrophilic interaction HPLC method for the determination of renal function biomarkers, creatinine and uric acid, in human fluids

Stereoselective interaction between hemoglobin and penicillamine enantiomers modified chiral surfaces

An optimized bioluminescent assay for inorganic sulfate quantitation in freshwater

Facile and sensitive paper-based chemiluminescence DNA biosensor using carbon dots dotted nanoporous gold signal amplification label

Near infrared spectroscopy combination with PLS to monitor the parameters of naproxen tablet preparation process

Novel separation for the determination of cadmium by isotope dilution ICP-MS in samples containing high concentrations of molybdenum and tin

An internal standard for protein purification by affinity sorption

Back cover

Analytical Methods Vol - 5 Issue - 4

Analytical Methods Vol - 5 Issue - 3

Analytical Methods Vol -4

Analytical Methods Vol -3

Analytical Methods Vol -2

Analytical Methods Vol -1

Fast chemical fingerprinting analysis for biodiesel/diesel blends using commercial solid phase extraction (SPE) cartridge and gas chromatography–mass spectrometry (GC–MS)

Content Provider	Royal Society of Chemistry (RSC)
Author	Yang, Zeyu Chen, Liya Pan, Zengkai Xie, Hongqin Ruan, Xinchao Xiong, Wei
Copyright Year	2013
Abstract	Commercially available solid phase extraction (SPE) cartridges were combined with GC–MS for fast cleanup and fractionation of biodiesel/diesel samples in oil fingerprinting analysis. Several commercially available SPE cartridges (e.g., silica gel/cyanopropyl (SiO2/C3–CN) and extractable petroleum hydrocarbons (EPH) fractionation cartridges), were employed for the fractionation of biodiesel/diesel blends into aliphatic, aromatic hydrocarbons, and fatty acid methyl esters (FAMEs). The SiO2/C3–CN (1 g/0.5 g) SPE cartridge could not separate biodiesel from petroleum hydrocarbons effectively, however, the 5 g EPH SPE cartridge successfully separated blended samples into aliphatic, aromatic and FAME fractions by eluting with 15 mL of hexane, 15 mL of dichloromethylene (DCM)/hexane (1 : 1, v/v), and 18 mL of DCM, respectively. No cross-elution was observed among aliphatic, aromatic and FAME fractions when the loading mass of blends was less than 8 mg. The relative standard deviations (RSD) for five replicate SPE–GC–MS analyses of 5 mg of diesel blended with 20% biodiesel (volume/volume) and soybean oil ranged from 3.4% to 33.2%, 4.3% to 18.7% and 5.4% to 29.2% for selected alkane, polycyclic aromatic hydrocarbons (PAHs) and FAMEs, respectively. The final recovery rates of surrogates for aliphatic, aromatic and FAME fractions ranged from 82.5 to 91.1%. This developed method was successfully used for the fingerprinting analysis of three simulated blend samples. The concentration profiles of target compounds and the blended level are both comparable to those obtained by the conventional silica gel column–GC–MS method.
Starting Page	1205
Ending Page	1213
Page Count	9
File Format	HTM / HTML PDF
ISSN	17599660
Volume Number	5
Issue Number	5
Journal	Analytical Methods
DOI	10.1039/c2ay26191j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Centerfire ammunition Solid phase extraction Cyanide Aliphatic compound Polycyclic aromatic hydrocarbon Biodiesel Petroleum DCM Fatty acid Hexane Silica gel Soybean oil Total petroleum hydrocarbon
Content Type	Text
Resource Type	Article
Subject	Analytical Chemistry Engineering Chemical Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Oil fingerprinting analysis using commercial solid phase extraction (SPE) cartridge and gas chromatography-mass spectrometry (GC-MS)

A simple method for the determination of polycyclic aromatic hydrocarbons (pah) in edible oil employing solid phase extraction (SPE) cartridge purification

Analysis of polycyclic aromatic hydrocarbons in the atmospheric particulate: focused microwaves for a faster extraction method

Quantification and characterization of naphthenic acids in soils from oil exploration areas in China by GC/MS

Determination of polycyclic aromatic hydrocarbons in water samples by hollow fiber extraction coupled with GC-MS

Graphene-Derivatized Silica Composite as Solid-Phase Extraction Sorbent Combined with GC–MS/MS for the Determination of Polycyclic Musks in Aqueous Samples

Determination of triclocarban in aquatic plants by using SPE combined with HPLC-ESI-MS/MS

Prediction of solid polycyclic aromatic hydrocarbons solubility in water with the nrtl-pr model (2013).

Evaluation of dispersive and cartridge SPE clean-up procedures using the modified QuEChERS method for the analysis of pesticides in strawberries

Fast chemical fingerprinting analysis for biodiesel/diesel blends using commercial solid phase extraction (SPE) cartridge and gas chromatography–mass spectrometry (GC–MS)

Similar Documents

Oil fingerprinting analysis using commercial solid phase extraction (SPE) cartridge and gas chromatography-mass spectrometry (GC-MS)

A simple method for the determination of polycyclic aromatic hydrocarbons (pah) in edible oil employing solid phase extraction (SPE) cartridge purification

Analysis of polycyclic aromatic hydrocarbons in the atmospheric particulate: focused microwaves for a faster extraction method

Quantification and characterization of naphthenic acids in soils from oil exploration areas in China by GC/MS

Determination of polycyclic aromatic hydrocarbons in water samples by hollow fiber extraction coupled with GC-MS

Graphene-Derivatized Silica Composite as Solid-Phase Extraction Sorbent Combined with GC–MS/MS for the Determination of Polycyclic Musks in Aqueous Samples

Determination of triclocarban in aquatic plants by using SPE combined with HPLC-ESI-MS/MS

Prediction of solid polycyclic aromatic hydrocarbons solubility in water with the nrtl-pr model (2013).

Evaluation of dispersive and cartridge SPE clean-up procedures using the modified QuEChERS method for the analysis of pesticides in strawberries

Fast chemical fingerprinting analysis for biodiesel/diesel blends using commercial solid phase extraction (SPE) cartridge and gas chromatography–mass spectrometry (GC–MS)