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Crystal structure of 4-fluoro-N-[2-(4-fluorobenzoyl)hydrazine-1-carbonothioyl]benzamide
| Content Provider | PubMed Central |
|---|---|
| Author | Firdausiah, Syadza Salleh, Huddin Ameera Aqeela Hasbullah, Siti Aishah Yamin, Bohari M. Yusoff, Siti Fairus M. |
| Copyright Year | 2014 |
| Abstract | In the title compound, C15H11F2N3O2S, the dihedral angle between the fluorobenzene rings is 88.43 (10)° and that between the central semithiocarbazide grouping is 47.00 (11)°. The dihedral angle between the amide group and attached fluorobenzene ring is 50.52 (11)°; the equivalent angle between the carbonylthioamide group and its attached ring is 12.98 (10)°. The major twists in the molecule occur about the C—N—N—C bonds [torsion angle = −138.7 (2)°] and the Car—Car—C—N (ar = aromatic) bonds [−132.0 (2)°]. An intramolecular N—H⋯O hydrogen bond occurs, which generates an S(6) ring. In the crystal, the molecules are linked by N—H⋯O and N—H⋯S hydrogen bonds, generating (001) sheets. Weak C—H⋯O and C—H⋯F interactions are also observed. |
| Related Links | http://dx.doi.org/10.1107/S1600536814015761 |
| Ending Page | 916 |
| Starting Page | 915 |
| File Format | |
| ISSN | 16005368 |
| e-ISSN | 16005368 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Issue Number | Pt 9 |
| Volume Number | 70 |
| Language | English |
| Publisher | International Union of Crystallography |
| Access Restriction | Open |
| Rights Holder | International Union of Crystallography |
| Subject Keyword | Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
