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| Content Provider | PubMed Central |
|---|---|
| Author | Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Chantrapromma, Suchada Fun, Hoong-kun |
| Copyright Year | 2014 |
| Abstract | In the title complex, [Pd(C16H16NO2)2]·CHCl3, the PdII cation lies on an inversion center. One Cl atom of the CHCl3 solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The PdII cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52 (10)° with that of the methoxyphenolate ring. In the crystal, molecules of the PdII complex are arranged into sheets parallel to the ac plane, and the chloroform solvent molecules are located in the interstitial areas between the complex molecules. Weak intermolecular C—H⋯O and C—H⋯π interactions stabilize the packing. |
| Related Links | http://dx.doi.org/10.1107/s1600536814015025 |
| Starting Page | 289 |
| File Format | |
| ISSN | 16005368 |
| e-ISSN | 16005368 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Issue Number | Pt 8 |
| Volume Number | 70 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2014-08-15 |
| Access Restriction | Open |
| Rights Holder | International Union of Crystallography |
| Subject Keyword | Materials Science(all) Chemistry(all) Condensed Matter Physics Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
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