NDLI: Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2 O,O′)cobaltate(II)

Content Provider	PubMed Central
Author	Saad, Ahlem Ben Selmi, Ahmed Mohamed, Rzaigui Toumi, Akriche Samah
Copyright Year	2014
Abstract	In the title compound, (C8H12N)2[Co(H2P2O7)2(H2O)2], the Co2+ ion lies on a crystallographic inversion centre and adopts a slightly distorted octahedral CoO6 coordination geometry arising from two chelating diphosphate [H2P2O7]2− ligands and two trans water molecules. In the crystal, the components are linked by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and weak aromatic π–π stacking [shortest centroid–centroid separation = 3.778 (2) Å] interactions. (001) layers of alternating organic cations and complex inorganic anions are apparent.
Related Links	http://dx.doi.org/10.1107/S1600536814002530
Ending Page	87
Starting Page	86
File Format	PDF
ISSN	16005368
e-ISSN	16005368
Journal	Acta Crystallographica Section E: Structure Reports Online
Issue Number	Pt 3
Volume Number	70
Language	English
Publisher	International Union of Crystallography
Access Restriction	Open
Rights Holder	International Union of Crystallography
Subject Keyword	Research in Higher Education
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ2 O,O′)cobaltate(II)