NDLI: (2,2′-Bipyridine)chlorido[diethyl (2,2′:6′,2′′-terpyridin-4-yl)phosphonate]ruthenium(II) hexafluoridophosphate acetonitrile/water solvate

Content Provider	PubMed Central
Author	Chen, Weizhong Rein, Francisca N. Scott, Brian L. Rocha, Reginaldo C.
Copyright Year	2013
Abstract	The cationic complex in the title compound, [RuCl(C10H8N2)(C19H20N3O3P)]PF6·0.83CH3CN·0.17H2O, is a water-oxidation precatalyst functionalized for TiO2 attachment via terpyridine phosphonate. The The RuII atom in the complex has a distorted octahedral geometry due to the restricted bite angle [159.50 (18)°] of the terpyridyl ligand. The dihedral angle between the least-squares planes of the terpyridyl and bipyridyl moieties is 86.04 (14)°. The mean Ru—N bond length for bipyridine is 2.064 (5) Å, with the bond opposite to Ru—Cl being 0.068 Å shorter. For the substituted terpyridine, the mean Ru—N distance involving the outer N atoms trans to each other is 2.057 (6) Å, whereas the bond length involving the central N atom is 1.944 (5) Å. The Ru—Cl distance is 2.4073 (15) Å. The P atom of the phosphonate group lies in the same plane as its adjacent pyridyl ring, with the ordinary character of the bond between P and Ctpy [1.801 (6) Å] allowing for free rotation of the terpyridine substituent around the P—Ctpy axis. The acetonitrile solvent molecule was refined to be disordered with two water molecules; occupancies for the acetontrile and water molecules were 0.831 (9) and 0.169 (9), respectively. Also disordered was the PF6 − counter-ion (over three positions) and one of the ethoxy substituents (with two positions). The crystal structure shows significant intra- and intermolecular H⋯X contacts, especially some involving the Cl− ligand.
Related Links	http://dx.doi.org/10.1107/s1600536813022940
Starting Page	510
File Format	PDF
ISSN	16005368
e-ISSN	16005368
Journal	Acta Crystallographica Section E: Structure Reports Online
Issue Number	Pt 9
Volume Number	69
Language	English
Publisher	International Union of Crystallography
Publisher Date	2013-09-15
Access Restriction	Open
Rights Holder	International Union of Crystallography
Subject Keyword	Materials Science(all) Chemistry(all) Condensed Matter Physics Research in Higher Education
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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(2,2′-Bipyridine)chlorido[diethyl (2,2′:6′,2′′-terpyridin-4-yl)phosphonate]ruthenium(II) hexafluoridophosphate acetonitrile/water solvate

Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phenyl]phosphonate

Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phenyl]phosphonate

Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphenyl)carbamoyl]-2,2′-bipyridine-4-carboxylate}ruthenium(II) bis[hexafluoridophosphate(V)]

Bis(2,2′-bipyridine){ethyl 4′-[N-(4-carbamoylphenyl)carbamoyl]-2,2′-bipyridine-4-carboxylate}ruthenium(II) bis[hexafluoridophosphate(V)]

4,4′-{[4-(2,2′:6′,2′′-Terpyridin-4′-yl)phenyl]imino}dibenzaldehyde

1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene

[2-(2,2′:4′,2′′-Terpyridin-6′-yl-κ2 N 1,N 1′)benzoato-κO]manganese(II) trihydrate

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(2,2′-Bipyridine)chlorido[diethyl (2,2′:6′,2′′-terpyridin-4-yl)phosphonate]ruthenium(II) hexafluoridophosphate acetonitrile/water solvate

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