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2-Aminobenzoic acid–4-[2-(pyridin-4-yl)ethyl]pyridine (2/1)
| Content Provider | PubMed Central |
|---|---|
| Author | Arman, Hadi D. Tiekink, Edward R. T. |
| Copyright Year | 2013 |
| Abstract | The asymmetric unit of the title co-crystal, C12H12N2·2C7H7NO2, comprises a centrosymmetric 4-[2-(pyridin-4-yl)ethyl]pyridine molecule and a 2-aminobenzoic acid molecule in a general position. The acid has a small twist between the carboxylic acid residue and the ring [dihedral angle = 7.13 (6)°] despite the presence of an intramolecular N—H⋯O(carbonyl) hydrogen bond. Three-molecule aggregates are formed via O—H⋯N(pyridyl) hydrogen bonds, and these are connected into supramolecular layers in the bc plane by N—H⋯O(carbonyl) hydrogen bonds and π–π interactions between pyridine and benzene rings [inter-centroid distance = 3.6332 (9) Å]. Layers are connected along the a axis by weak π–π interactions between benzene rings [3.9577 (10) Å]. |
| Related Links | http://dx.doi.org/10.1107/S1600536813027128 |
| Starting Page | 1616 |
| File Format | |
| ISSN | 16005368 |
| e-ISSN | 16005368 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Issue Number | Pt 11 |
| Volume Number | 69 |
| Language | English |
| Publisher | International Union of Crystallography |
| Access Restriction | Open |
| Rights Holder | International Union of Crystallography |
| Subject Keyword | Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
