NDLI: (2,2′-Bipyridyl-κ2 N,N′)bis(η5-pentamethylcyclopentadienyl)barium

Content Provider	PubMed Central
Author	Kazhdan, Daniel Rozenel, Sergio S.
Copyright Year	2013
Abstract	In the title compound, [Ba(C10H15)2(C10H8N2)], the Ba—N distances are 2.798 (3) and 2.886 (3) Å, and the Cp ring centroid distances to Ba2+ are 2.7291 (7) and 2.7192 (9) Å. The angle between the N atoms in the bypyridine ligand and the metal ion is 56.80 (8)° and the N—C—C—N torsion angle in the bipyridine ligand is 1.7 (4)°. The bipyridine ligand is almost planar, the dihedral angle formed by the intersection of the planes defined by the pyridyl rings being 3.04 (19)°, and the angle between the plane defined by the Ba2+ ion and the two bipyridyl N atoms and the plane defined by the 12 atoms of the bipyridine ligand is 10.2 (3)°. The average Ba—N and Ba—centroid distances are 0.16 and 0.14 Å longer, respectively, than the equivalent distances in the isotypic strontium compound [Kazhdan et al. (2008 ▶). Acta Cryst. E64, m1134]. This difference is in accord with the difference between the ionic radii of 0.16 Å suggested by Shannon [Acta Cryst. (1976 ▶), A32, 751–767].
Related Links	http://dx.doi.org/10.1107/s1600536813017170
Starting Page	429
File Format	PDF
ISSN	16005368
e-ISSN	16005368
Journal	Acta Crystallographica Section E: Structure Reports Online
Issue Number	Pt 8
Volume Number	69
Language	English
Publisher	International Union of Crystallography
Publisher Date	2013-08-15
Access Restriction	Open
Rights Holder	International Union of Crystallography
Subject Keyword	Materials Science(all) Chemistry(all) Condensed Matter Physics Research in Higher Education
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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(2,2-Bipyridyl)bis(η5-pentamethylcyclopentadienyl)strontium(II)

$(2,2′-Bipyridyl-κ^{2}$ $N,N′)bis(η^{5}-pentamethylcyclopentadienyl)barium$

(Cyanido-κC)(2,2-diphenylacetamido-κ2 N,O)bis(η5-pentamethylcyclopentadienyl)zirconium(IV)

Di-μ-hydroxido-κ4 O:O-μ-trifluoromethanesulfonato-κ2 O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2 N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine

(2,2′-Bipyridyl)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2 S,S′]cadmium(II)

(2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2 S,S′]cadmium(II) acetonitrile solvate

(Glycol-κ2 O,O′)nitrosyl(η5-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate)

(Glycol-κ2 O,O′)nitrosyl(η5-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate). Corrigendum

$(2,2-Bipyridyl)bis(η^{5}-pentamethylcyclopentadienyl)strontium(II)$

(2,2′-Bipyridyl-κ2 N,N′)bis(η5-pentamethylcyclopentadienyl)barium

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