NDLI: A solution to the stereochemical problems posed by amaryllidaceae constituents using a highly syn-selective arylcuprate conjugate addition to γ-amino and γ-carbamato-α,β-enoates

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Content Provider	PubMed Central
Author	Rastogi, Shiva K. Kornienko, Alexander
Copyright Year	2006
Abstract	Various substituted arylcuprates undergo stereocontrolled additions to L-serine-derived γamino- and γ-carbamato-α,β-enoates with high syn-selectivities. The stereochemical outcome of these reactions is fully consistent with the reductive elimination-based model proposed previously. This method is well suited for the preparation of a broad range of biologically active amaryllidaceae constituents and their aromatic analogues.
Related Links	http://dx.doi.org/10.1016/j.tetasy.2006.11.029
Ending Page	3178
Page Count	9
Starting Page	3170
File Format	PDF
ISSN	09574166
e-ISSN	1362511X
Journal	Tetrahedron, asymmetry
Issue Number	22
Volume Number	17
Language	English
Publisher Date	2006-11-01
Access Restriction	Open
Subject Keyword	Physical and Theoretical Chemistry Inorganic Chemistry Organic Chemistry Catalysis Research in Higher Education
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Physical and Theoretical Chemistry Catalysis Inorganic Chemistry

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A solution to the stereochemical problems posed by amaryllidaceae constituents using a highly syn-selective arylcuprate conjugate addition to γ-amino and γ-carbamato-α,β-enoates