NDLI: catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate]

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catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate]

Content Provider	PubMed Central
Author	Farag, Abeer Mohamed Guan, Teoh Siang Osman, Hasnah Madhukar, Hemamalini Fun, Hoong-kun
Copyright Year	2012
Abstract	The asymmetric unit of the title complex, {[Mn(C20H10Br2N3O5)(H2O)]·(CH3)2NCHO} n , consists of one MnIII ion, one (E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidate ligand (Schiff base), one water molecule and an N,N-dimethylformamide molecule. The coordination geometry around the MnIII ion is a distorted octahedron, being surrounded by two O and two N atoms from the Schiff base, which are positioned in the equatorial plane. The water molecule and the O atom of the carbonyl group from the adjacent MnIII complex are situated at the axial positions, leading to a polymeric chain along the c axis. In the crystal, the complex and N,N-dimethylformamide molecules are connected via O—H⋯O, C—H⋯O and C—H⋯Br hydrogen bonds, forming a three-dimensional network.
Related Links	http://dx.doi.org/10.1107/S1600536812008501
Ending Page	366
Starting Page	365
File Format	PDF
ISSN	16005368
e-ISSN	16005368
Journal	Acta Crystallographica Section E: Structure Reports Online
Issue Number	Pt 4
Volume Number	68
Language	English
Publisher	International Union of Crystallography
Access Restriction	Open
Rights Holder	International Union of Crystallography
Subject Keyword	Research in Higher Education
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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