NDLI: A potential anticancer agent: 5-chloro-7-iodo-8-hydroxyquinolinium dichlorido(5-chloro-7-iodoquinolin-8-olato-κ2 N,O)palladium(II) dihydrate

Content Provider	PubMed Central
Author	Peter, Vranec Ivan, Potočňák
Copyright Year	2011
Abstract	The title PdII coordination compound, (C9H6ClINO)[PdCl2(C9H4ClINO)]·2H2O, was prepared as a potential anticancer agent. Its structure is ionic and consists of a square-planar [PdCl2(CQ)]− complex anion (CQ is 5-chloro-7-iodoquinolin-8-olate), with the PdII atom surrounded by two chloride ligands in a cis configuration and one N,O-bidentate CQ molecule, a protonated anion of CQ as counter-cation and two non-coordinated water molecules. The water molecules are involved in O—H⋯O and N—H⋯O hydrogen bonds, which interconnect the HCQ+ cations into a chain parallel to [010]. Apart from these interactions, the structure is also stabilized by face-to-face π–π interactions [centroid–centroid = 3.546 (3) Å], which occur between the phenolic parts of the complex anions and cations.
Related Links	http://dx.doi.org/10.1107/s1600536811040803
Starting Page	1508
File Format	PDF
ISSN	16005368
e-ISSN	16005368
Journal	Acta Crystallographica Section E: Structure Reports Online
Issue Number	Pt 11
Volume Number	67
Language	English
Publisher	International Union of Crystallography
Publisher Date	2011-11-15
Access Restriction	Open
Rights Holder	International Union of Crystallography
Subject Keyword	Materials Science(all) Chemistry(all) Condensed Matter Physics Research in Higher Education
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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A potential anticancer agent: 5-chloro-7-iodo-8-hydroxyquinolinium dichlorido(5-chloro-7-iodoquinolin-8-olato-κ2 N,O)palladium(II) dihydrate