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| Content Provider | PubMed Central |
|---|---|
| Author | Zhu, Xiao-hong Cheng, Xiao-chun |
| Copyright Year | 2011 |
| Abstract | In the title polymer, {[Co(C14H10N2O4)(H2O)]·3.5H2O} n , the Co2+ ion is coordinated by three carboxylate O atoms from two 5-[(pyridin-2-ylmethyl)amino]isophthalate anions, two N atoms from a (pyridin-2-ylmethyl)amino group and an O atom from a water molecule, furnishing a distorted CoO4N2 octahedral geometry. Each anion acts as a μ3-bridge, linking cobalt ions into a two-dimensional layer parallel to (100). The asymmetric unit also contains three and a half solvent water molecules, which could not be modeled. Therefore, the diffraction contribution of the solvent water molecules was removed by the subroutine SQUEEZE in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. The crystal structure is stabilized by O—H⋯O hydrogen bonds in which the coordinated water molecule acts as donor and the carboxylate O atoms as acceptors. |
| Related Links | http://dx.doi.org/10.1107/s1600536811050318 |
| Starting Page | 1862 |
| File Format | |
| ISSN | 16005368 |
| e-ISSN | 16005368 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Issue Number | Pt 12 |
| Volume Number | 67 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2011-12-15 |
| Access Restriction | Open |
| Rights Holder | International Union of Crystallography |
| Subject Keyword | Materials Science(all) Chemistry(all) Condensed Matter Physics Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
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