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| Content Provider | PubMed Central |
|---|---|
| Author | Barber, Patrick S. De, Bettencourt-dias Ana |
| Copyright Year | 2011 |
| Abstract | The title complex, [Nd(C8H4F3O2S)3(H2O)2]·CH3CN, consists of an NdIII ion surrounded by three 4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-olate ligands, coordinated through the O atoms, and two water molecules. The Nd—O bond lengths range from 2.372 (2) to 2.513 (2) Å. The metal ion displays a coordination number of eight and a square-antiprismatic coordination geometry. A single uncoordinated acetonitrile molecule is present in the asymmetric unit. Two of the three thiophene rings are disordered, resulting from a 180° rotation with respect to the β-diketonate moiety. The coordinated water molecules act as hydrogen-bond donors towards the acetonitrile N atom and the β-diketonate O atoms. |
| Related Links | http://dx.doi.org/10.1107/s1600536811030376 |
| Starting Page | 1188 |
| File Format | |
| ISSN | 16005368 |
| e-ISSN | 16005368 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Issue Number | Pt 9 |
| Volume Number | 67 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2011-09-15 |
| Access Restriction | Open |
| Rights Holder | International Union of Crystallography |
| Subject Keyword | Materials Science(all) Chemistry(all) Condensed Matter Physics Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
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