NDLI: 2-[(1-{[3-(dimethylazaniumyl)propyl]methylamino}ethylidene)azaniumyl]nonahydro-closo-decaborate dimethyl sulfoxide disolvate

Content Provider	PubMed Central
Author	Getman, Thomas D. Luck, Rudy L. Cienkus, Caitlin
Copyright Year	2011
Abstract	The title compound, 2-B10H9NH=C(CH3)N(CH3)CH2CH2CH2N(CH3)2H·2C2H6OS or C8H29B10N3·2C2H6OS, is zwitterionic with the negative charge localized on the decaborate cage and the positive charge on the terminal ammonium group. Two molecules of dimethyl sulfoxide (DMSO) and one molecule of the title compound constitute the asymmetric unit. One DMSO molecule is disordered [ratio 0.739 (3):0.261 (3)]. The bonds and angles within the decaborate cage are within the normal ranges. The amidine fragment of the ligand, which is expected to be planar, is significantly distorted from planarity as exemplified by four torsion angles [B—N—C—C = 8.4 (3), H—N—C—N = 5(2), N—C—N—C = 7.3 (3) and C—C—N—C = 14.8 (3)°] found within this portion of the molecule. The crystal packing consists of head-to-tail-arranged dimers of the title molecule held together by four molecules of DMSO which are attached via strong N—H⋯O and weak C—H⋯O hydrogen bonds.
Related Links	http://dx.doi.org/10.1107/s1600536811020186
Starting Page	1682
File Format	PDF
ISSN	16005368
e-ISSN	16005368
Journal	Acta Crystallographica Section E: Structure Reports Online
Issue Number	Pt 7
Volume Number	67
Language	English
Publisher	International Union of Crystallography
Publisher Date	2011-07-15
Access Restriction	Open
Rights Holder	International Union of Crystallography
Subject Keyword	Materials Science(all) Chemistry(all) Condensed Matter Physics Research in Higher Education
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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