NDLI: 2,4-Bis(2-methylphenyl)-3-azabicyclo[3.3.1]nonan-9-one O-methyloxime

Content Provider	PubMed Central
Author	Parthiban, P. Ramkumar, V. Jeong, Yeon Tae
Copyright Year	2010
Abstract	The molecule of the title compound, C23H28N2O, exists in a twin-chair conformation, with equatorial orientation of the ortho-tolyl groups on both sides of the secondary amino group. The title oxime compound and its ketone precursor 2,4-bis(2-methylphenyl)-3-azabicyclo[3.3.1]nonan-9-one exhibit similar stereochemistries, with the orientation of the o-tolyl rings almost identical in both compounds. In the title compound, the tolyl rings are at an angle of 23.77 (3)° with respect to one another; the angle in the precursor is 29.4 (1)° [Vijayalakshmi, Parthasarathi, Venkatraj & Jeyaraman (2000 ▶), Acta Cryst. C56, 1240–1241]. The cyclohexane ring and the oxime ether are disordered over two alternative orientations, with a refined site-occupancy ratio of 0.813 (2):0.186 (4). The crystal structure of the title compound is stabilized by intermolecular N—H⋯π interactions.
Related Links	http://dx.doi.org/10.1107/s1600536810043436
Starting Page	2978
File Format	PDF
ISSN	16005368
e-ISSN	16005368
Journal	Acta Crystallographica Section E: Structure Reports Online
Issue Number	Pt 11
Volume Number	66
Language	English
Publisher	International Union of Crystallography
Publisher Date	2010-11-15
Access Restriction	Open
Rights Holder	International Union of Crystallography
Subject Keyword	Materials Science(all) Chemistry(all) Condensed Matter Physics Research in Higher Education
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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Crystal structure of 2,4-bis(2-chlorophenyl)-7-tert-pentyl-3-azabicyclo[3.3.1]nonan-9-one

2,4-Bis(2-ethoxyphenyl)-3-azabicyclo[3.3.1]nonan-9-one

2,4-Bis(2-bromophenyl)-3-azabicyclo[3.3.1]nonan-9-one

2,4-Bis(2-chlorophenyl)-3-azabicyclo[3.3.1]nonan-9-one

2,4-Bis(2-fluorophenyl)-3-azabicyclo[3.3.1]nonan-9-one

2,4-Bis(2-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-9-one

2,4-Bis(2-ethoxyphenyl)-7-methyl-3-azabicyclo[3.3.1]nonan-9-one

2,4-Bis(2-fluorophenyl)-1-methyl-3-azabicyclo[3.3.1]nonan-9-one

2,4-Bis(3-bromophenyl)-3-azabicyclo[3.3.1]nonan-9-one

2,4-Bis(2-methylphenyl)-3-azabicyclo[3.3.1]nonan-9-one O-methyloxime

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