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Triazido[tris(2-pyridyl-κN)methylamine]cobalt(III)
| Content Provider | PubMed Central |
|---|---|
| Author | Hao, Lujiang Liu, Xia |
| Copyright Year | 2008 |
| Abstract | The title compound, [Co(N3)3(C16H14N4)], was synthesized by hydrothermal reaction of [Co(NH3)6](NO3)3, NaN3 and tris(2-pyridyl)methylamine. The structure contains two independent complexes in the asymmetric unit, with closely comparable geometry. The CoIII atoms are hexacoordinated by three N atoms from the tridentate tris(2-pyridyl)methylamine ligands and three azide ions in a fac arrangement. N—H⋯N hydrogen bonds are formed between the amino group and the uncoordinated terminal N atoms of the azide ligands. |
| Related Links | http://dx.doi.org/10.1107/S1600536808035162 |
| Starting Page | 1499 |
| File Format | |
| ISSN | 16005368 |
| e-ISSN | 16005368 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Issue Number | Pt 12 |
| Volume Number | 64 |
| Language | English |
| Publisher | International Union of Crystallography |
| Access Restriction | Open |
| Rights Holder | International Union of Crystallography |
| Subject Keyword | Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |