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| Content Provider | PubMed Central |
|---|---|
| Author | Sato, Yohei Uta, Kazuya Mizuguchi, Jin |
| Copyright Year | 2008 |
| Abstract | The title compound, [Fe2Na2(C23H14ClN3O3)4(C2H3N)2(H2O)4]·2H2O, is a hydrated Fe–azo complex dimer that is used as a charge-control agent in electrophotography. The molecule is a centrosymmetric dimer with two octahedral FeIII units linked by two bridging five-coordinate NaI cations. Each FeIII atom is chelated by the N and two O atoms from two 3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The Na+ cation is coordinated by a carbonyl O atom from the two ligands of each octahedral FeIII unit, two water molecules and the N atom of an acetonitrile molecule. Two solvent water molecules complete the structure. In the crystal structure, the dimeric molecules are bridged by a pair of discrete intermolecular O—H⋯O hydrogen bonds, one of which involves a sodium-bound water molecule and a hydrate water, and the other a 5-chlorophenolate O atom and a water molecule to form an extended chain along b. |
| Related Links | http://dx.doi.org/10.1107/s1600536807066895 |
| Starting Page | 240 |
| File Format | |
| ISSN | 16005368 |
| e-ISSN | 16005368 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Issue Number | Pt 1 |
| Volume Number | 64 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2008-01-15 |
| Access Restriction | Open |
| Rights Holder | International Union of Crystallography |
| Subject Keyword | Materials Science(all) Chemistry(all) Condensed Matter Physics Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
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