Please wait, while we are loading the content...
Please wait, while we are loading the content...
| Content Provider | PubMed Central |
|---|---|
| Author | Finkelstein, Ilya J. Mcclain, Brian L. Fayer, M. D. |
| Abstract | The fifth order contributions to the signals of ultrafast infrared spectrally resolved stimulated vibrational echoes at high intensities have been investigated in carbonmonoxy heme proteins. High intensities are often required to obtain good data. Intensity dependent measurements are presented on hemoglobin-CO (Hb–CO) and a mutant of myoglobin, H64V–CO. The spectrally resolved vibrational echoes demonstrate that fifth order effects arise at both the 1-0 and the 2-1 emission frequencies of the stretching mode of the CO chromophore bound at the active site of heme proteins. Unlike one-dimensional experiments, in which the signal is integrated over all emission frequencies, spectrally resolving the signal shows that the fifth order contributions have a much more pronounced influence on the 2-1 transition than on the 1-0 transition. By spectrally isolating the 1-0 transition, the influence of fifth order contributions to vibrational echo data can be substantially reduced. Analysis of fifth order Feynman diagrams that contribute in the vibrational echo phase-matched direction demonstrates the reason for the greater influence of fifth order processes on the 1-2 transition, and that the fifth order contributions are heterodyne amplified by the third order signal. Finally, it is shown that the anharmonic oscillations in vibrational echo data of Hb–CO that previous work had attributed strictly to fifth order effects arise even without fifth order contributions. |
| Related Links | http://dx.doi.org/10.1063/1.1758940 |
| Starting Page | 877 |
| File Format | |
| ISSN | 00219606 |
| e-ISSN | 10897690 |
| Journal | The Journal of chemical physics |
| Issue Number | 2 |
| Volume Number | 121 |
| Language | English |
| Publisher Date | 2004-01-01 |
| Access Restriction | Open |
| Subject Keyword | Physical and Theoretical Chemistry Physics and Astronomy(all) Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physics and Astronomy Medicine Physical and Theoretical Chemistry |
National Digital Library of India (NDLI) is a virtual repository of learning resources which is not just a repository with search/browse facilities but provides a host of services for the learner community. It is sponsored and mentored by Ministry of Education, Government of India, through its National Mission on Education through Information and Communication Technology (NMEICT). Filtered and federated searching is employed to facilitate focused searching so that learners can find the right resource with least effort and in minimum time. NDLI provides user group-specific services such as Examination Preparatory for School and College students and job aspirants. Services for Researchers and general learners are also provided. NDLI is designed to hold content of any language and provides interface support for 10 most widely used Indian languages. It is built to provide support for all academic levels including researchers and life-long learners, all disciplines, all popular forms of access devices and differently-abled learners. It is designed to enable people to learn and prepare from best practices from all over the world and to facilitate researchers to perform inter-linked exploration from multiple sources. It is developed, operated and maintained from Indian Institute of Technology Kharagpur.
Learn more about this project from here.
NDLI is a conglomeration of freely available or institutionally contributed or donated or publisher managed contents. Almost all these contents are hosted and accessed from respective sources. The responsibility for authenticity, relevance, completeness, accuracy, reliability and suitability of these contents rests with the respective organization and NDLI has no responsibility or liability for these. Every effort is made to keep the NDLI portal up and running smoothly unless there are some unavoidable technical issues.
Ministry of Education, through its National Mission on Education through Information and Communication Technology (NMEICT), has sponsored and funded the National Digital Library of India (NDLI) project.
| Sl. | Authority | Responsibilities | Communication Details |
|---|---|---|---|
| 1 | Ministry of Education (GoI), Department of Higher Education |
Sanctioning Authority | https://www.education.gov.in/ict-initiatives |
| 2 | Indian Institute of Technology Kharagpur | Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project | https://www.iitkgp.ac.in |
| 3 | National Digital Library of India Office, Indian Institute of Technology Kharagpur | The administrative and infrastructural headquarters of the project | Dr. B. Sutradhar bsutra@ndl.gov.in |
| 4 | Project PI / Joint PI | Principal Investigator and Joint Principal Investigators of the project |
Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon |
| 5 | Website/Portal (Helpdesk) | Queries regarding NDLI and its services | support@ndl.gov.in |
| 6 | Contents and Copyright Issues | Queries related to content curation and copyright issues | content@ndl.gov.in |
| 7 | National Digital Library of India Club (NDLI Club) | Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach | clubsupport@ndl.gov.in |
| 8 | Digital Preservation Centre (DPC) | Assistance with digitizing and archiving copyright-free printed books | dpc@ndl.gov.in |
| 9 | IDR Setup or Support | Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops | idr@ndl.gov.in |
|
Loading...
|