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Differentiation of chiral phosphorus enantiomers by 31P and 1H NMR spectroscopy using amino acid derivatives as chemical solvating agents
| Content Provider | PubMed Central |
|---|---|
| Author | Li, Yingchun Raushel, Frank M. |
| Abstract | The ability of commercially available amino acid derivatives, especially Fmoc-Trp(Boc)-OH, to differentiate enantiomers of chiral phosphonates, phosphinates, phosphates, phosphine oxides, and phosphonamidates is demonstrated with 31P, 13C, and 1H NMR spectroscopy. The chiral differentiation provided a rapid and convenient method for measuring the enantiomeric purity of these phosphorus compounds. |
| Related Links | http://dx.doi.org/10.1016/j.tetasy.2007.06.012 |
| Starting Page | 1391 |
| File Format | |
| ISSN | 1362511X |
| e-ISSN | 1362511X |
| Journal | Tetrahedron, asymmetry |
| Issue Number | 12 |
| Volume Number | 18 |
| Language | English |
| Publisher Date | 2007-07-04 |
| Access Restriction | Open |
| Subject Keyword | Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Physical and Theoretical Chemistry Catalysis Inorganic Chemistry |
