NDLI: Selective liquid-phase oxidation of allyl alcohol to glycidol over MWW type titanosilicalite

Content Provider	Paperity
Author	Wróblewska, Agnieszka Milchert, Eugeniusz Fajdek, Anna
Abstract	The results of the epoxidation of allyl alcohol with 30% hydrogen peroxide over the Ti-MWW catalyst have been presented. The studies were carried out under atmospheric pressure and in the presence of methanol as a solvent. The influence of the following technological parameters on the course of epoxidation was examined: temperature (20–60 °C), the molar ratio of AA/H2O2 (1:1–5:1), methanol concentration (5–90 wt%), catalyst content (0–5.0 wt%), reaction time (5–300 min) and intensity of stirring (0–500 rpm).
Starting Page	451
Ending Page	462
File Format	HTM / HTML
ISSN	18785190
DOI	10.1007/s11144-011-0312-5
Issue Number	2
Journal	Reaction Kinetics, Mechanisms and Catalysis
Volume Number	103
e-ISSN	18785204
Language	English
Publisher	Springer International Publishing
Publisher Date	2011-08-01
Access Restriction	Open
Subject Keyword	Ti-mww catalyst Hydrogen peroxide Glycidol Liquid-phase epoxidation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Catalysis

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Selective liquid-phase oxidation of allyl alcohol to glycidol over MWW type titanosilicalite