Loading...
Please wait, while we are loading the content...
Similar Documents
Quinaldinium Chlorochromate(VI), (QnCC) Catalyzed Oxidation of Alcohols with Periodic Acid Under Solvent-Free Conditions and Microwave Irradition
| Content Provider | Paperity |
|---|---|
| Author | Ă–zdemir, Melek Canbulat |
| Abstract | The economic synthesis of quinaldinium chlorochromate(VI), C 10 H 9 NH[CrO 3 Cl], (QnCC) was performed by using a 1:1:1 stoichiometric amounts of CrO 3 , HCl (aq) and quinaldine. QnCC was isolated in 99% yield as an orange crystalline solid and characterized with FT-IR, 1 H-NMR, and 13 C-NMR. An efficient, selective, and environmentally friendly oxidation of alcohols with 1.1 equiv. periodic acid (H 5 IO 6 ) catalyzed by QnCC (2 mol%) is described. The primary and secondary alcohols were oxidized to their corresponding aldehydes and ketones under solvent-free conditions at room temperature and MW irradiation in high to excellent yields. |
| Starting Page | 679 |
| Ending Page | 690 |
| File Format | HTM / HTML |
| DOI | 10.18596/jotcsa.357452 |
| Issue Number | 5 |
| Journal | Journal of the Turkish Chemical Society, Section A: Chemistry |
| Volume Number | 2 |
| Language | English |
| Publisher | Turkish Chemical Society |
| Publisher Date | 2018-01-01 |
| Access Restriction | Open |
| Subject Keyword | Microwave irradiation Quinaldinium chlorochromate Periodic acid Solvent-free Alcohols |
| Content Type | Text |
| Resource Type | Article |