NDLI: Metal halide-group III halide gas complexes with emphasis on aluminum chloride

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Metal halide-group III halide gas complexes with emphasis on aluminum chloride

Content Provider	United States Department of Energy Office of Scientific and Technical Information (OSTI.GOV)
Author	Oeye, H. A. Gruen, D. M.
Organization	Argonne National Lab., IL (USA)
Abstract	The thermodynamics of the presently known gas complexation reactions between metal halides and group III halides are treated in a self-consistent manner. By focusing on aluminum chloride as a complexing agent, certain systematic trends are revealed. The partial pressures of the gaseous complexes display shallow minima near 800/sup 0/K whenever the complex molecules involve more than one molecule of AlCl/sub 3/. Increasing the aluminum chloride pressure from 1 atm. to 10/sup 3/ atm. decreases somewhat the differences in the partial pressures among the various gaseous complexes which span two to three orders of magnitude. The methods developed for characterizing the complexes, and their structures as well as some applications of gas complexation are discussed.
Related Links	https://www.osti.gov/biblio/6514511
Page Count	36
File Format	PDF
Language	English
Publisher Date	1978-01-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	PHYSICAL AND ANALYTICAL CHEMISTRY INORGANIC ORGANIC ALUMINIUM CHLORIDES CHEMICAL REACTIONS HALIDES COMPLEXES GASES PRESSURE DEPENDENCE REVIEWS THERMODYNAMICS ALUMINIUM COMPOUNDS CHLORIDES CHLORINE COMPOUNDS DOCUMENT TYPES FLUIDS HALOGEN COMPOUNDS Chemical & Physicochemical Properties
Content Type	Text
Resource Type	Article

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