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Lithium salts for advanced lithium batteries: Li-metal, Li-O₂, and Li-S

Content Provider	United States Department of Energy Office of Scientific and Technical Information (OSTI.GOV)
Author	Younesi, Reza Veith, Gabriel M. Johansson, Patrik Edstrom, Kristina Vegge, Tejs
Organization	Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Abstract	Presently lithium hexafluorophosphate (LiPF₆) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF₆ is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O₂), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical and chemical reactions and conditions within such cells. Furthermore, this review explores the critical role Li-salts play in ensuring in these batteries viability.
Sponsorship	USDOE Office of Science (SC)
Related Links	https://www.osti.gov/biblio/1195810
Starting Page	1905
Ending Page	1922
Page Count	18
File Format	PDF
ISSN	17545692
DOI	10.1039/C5EE01215E
Journal	Energy & Environmental Science
Volume Number	8
Issue Number	7
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2015-06-01
Publisher Place	United States
Access Restriction	Open
Subject Keyword	ENERGY STORAGE MATERIALS SCIENCE
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Pollution Renewable Energy, Sustainability and the Environment Nuclear Energy and Engineering

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