NDLI: Catalytic conversion of syngas to mixed alcohols over Zn-Mn promoted Cu-Fe based catalyst

Please wait, while we are loading the content...

Catalytic conversion of syngas to mixed alcohols over Zn-Mn promoted Cu-Fe based catalyst

Content Provider	United States Department of Energy Office of Scientific and Technical Information (OSTI.GOV)
Author	Lu, Yongwu Yu, Fei Hu, Jin Liu, Jian
Organization	Mississippi State Univ., Mississippi State, MS (United States)
Abstract	Zn-Mn promoted Cu-Fe based catalyst was synthesized by the co-precipitation method. Mixed alcohols synthesis from syngas was studied in a half-inch tubular reactor system after the catalyst was reduced. Zn-Mn promoted Cu-Fe based catalyst was characterized by SEM-EDS, TEM, XRD, and XPS. The liquid phase products (alcohol phase and hydrocarbon phase) were analyzed by GC-MS and the gas phase products were analyzed by GC. The results showed that Zn-Mn promoted Cu-Fe based catalyst had high catalytic activity and high alcohol selectivity. The maximal CO conversion rate was 72%, and the yield of alcohol and hydrocarbons were also very high. Cu (111) was the active site for mixed alcohols synthesis, Fe₂C (101) was the active site for olefin and paraffin synthesis. The reaction mechanism of mixed alcohols synthesis from syngas over Zn-Mn promoted Cu-Fe based catalyst was proposed. Here, Zn-Mn promoted Cu-Fe based catalyst can be regarded as a potential candidate for catalytic conversion of biomass-derived syngas to mixed alcohols.
Sponsorship	USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Related Links	https://www.osti.gov/biblio/1079498
Starting Page	48
Ending Page	58
Page Count	11
File Format	PDF
ISSN	0926860X
DOI	10.1016/j.apcata.2012.04.005
Journal	Applied Catalysis. A, General
Volume Number	429
Issue Number	430 (C)
Language	English
Publisher	Elsevier
Publisher Date	2012-04-12
Publisher Place	United States
Access Restriction	Open
Subject Keyword	INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY mixed alcohols synthesis syngas Zn-Mn promoted Cu- Fe based catalyst co-precipitation
Content Type	Text
Resource Type	Article
Subject	Catalysis Process Chemistry and Technology

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis Gas Conversion over Rh-Based Catalysts Promoted by Fe and Mn

Cu-Promoted Iron Catalysts Supported on Nanorod-Structured Mn-Ce Mixed Oxides for Higher Alcohol Synthesis from Syngas

Synthesis of Higher Alcohols from Syngas over Fe/K/β-Mo2C Catalyst

Catalytic activity of Cu–Zn–Al–Mn admixed with gamma-alumina for the synthesis of DME from syngas: manganese effect or just method of preparation?

Mixed Alcohol Dehydration over Bronsted and Lewis Acidic Catalysts

Effect of Zr addition on catalytic performance of Cu-Zn-Al oxides for CO$_{2}$ hydrogenation to methanol

Carbon nanotube-promoted Co-Cu catalyst for highly efficient synthesis of higher alcohols from syngas.

Ni/ADM: a high activity and selectivity to C$_{2+}$OH catalyst for catalytic conversion of synthesis gas to C$_{1}$-C$_{5}$ mixed alcohols

How to stabilize highly active Cu⁺ cations in a mixed-oxide catalyst

Catalytic conversion of syngas to mixed alcohols over Zn-Mn promoted Cu-Fe based catalyst

Similar Documents

Synthesis Gas Conversion over Rh-Based Catalysts Promoted by Fe and Mn

Cu-Promoted Iron Catalysts Supported on Nanorod-Structured Mn-Ce Mixed Oxides for Higher Alcohol Synthesis from Syngas

Synthesis of Higher Alcohols from Syngas over Fe/K/β-Mo2C Catalyst

Catalytic activity of Cu–Zn–Al–Mn admixed with gamma-alumina for the synthesis of DME from syngas: manganese effect or just method of preparation?

Mixed Alcohol Dehydration over Bronsted and Lewis Acidic Catalysts

Effect of Zr addition on catalytic performance of Cu-Zn-Al oxides for CO$_{2}$ hydrogenation to methanol

Carbon nanotube-promoted Co-Cu catalyst for highly efficient synthesis of higher alcohols from syngas.

Ni/ADM: a high activity and selectivity to C$_{2+}$OH catalyst for catalytic conversion of synthesis gas to C$_{1}$-C$_{5}$ mixed alcohols

How to stabilize highly active Cu+ cations in a mixed-oxide catalyst

Catalytic conversion of syngas to mixed alcohols over Zn-Mn promoted Cu-Fe based catalyst

How to stabilize highly active Cu⁺ cations in a mixed-oxide catalyst