Loading...
Please wait, while we are loading the content...
Similar Documents
Synthesis of New Derivatives of BEDT-TTF: Installation of Alkyl, Ethynyl, and Metal-Binding Side Chains and Formation of Tris(BEDT-TTF) Systems
| Content Provider | MDPI |
|---|---|
| Author | Yang, Songjie Zecchini, Matteo Brooks, Andrew Krivickas, Sara Dalligos, Desiree Matuszek, Anna Stares, Emma Pilkington, Melanie Wallis, John |
| Copyright Year | 2021 |
| Description | The syntheses of new BEDT-TTF derivatives are described. These comprise BEDT-TTF with one ethynyl group (HC≡C-), with two (n-heptyl) or four (n-butyl) alkyl side chains, with two trans acetal $(-CH(OMe)_{2}$) groups, with two trans aminomethyl $(-CH_{2}NH_{2}$) groups, and with an iminodiacetate (-CH_{2}N(CH_{2}CO_{2}^{−}$)_{2}$ side chain. Three transition metal salts have been prepared from the latter donor, and their magnetic properties are reported. Three tris-donor systems are reported bearing three BEDT-TTF derivatives with ester links to a core derived from benzene-1,3,5-tricarboxylic acid. The stereochemistry and molecular structure of the donors are discussed. X-ray crystal structures of two BEDT-TTF donors are reported: one with two $CH(OMe)_{2}$ groups and with one a $-CH_{2}N(CH_{2}CO_{2}Me)_{2}$ side chain. |
| Starting Page | 110 |
| e-ISSN | 23127481 |
| DOI | 10.3390/magnetochemistry7080110 |
| Journal | Magnetochemistry |
| Issue Number | 8 |
| Volume Number | 7 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2021-08-03 |
| Access Restriction | Open |
| Subject Keyword | Magnetochemistry Medicinal Chemistry Organic Chemistry Organic Conductors Bedt-ttf Synthesis Magnetism Crystal Structures |
| Content Type | Text |
| Resource Type | Article |
