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Carbones and Carbon Atom as Ligands in Transition Metal Complexes
| Content Provider | MDPI |
|---|---|
| Author | Zhao, Lili Chai, Chaoqun Petz, Wolfgang Frenking, Gernot |
| Copyright Year | 2020 |
| Description | This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (σ and π) donation to the metal atom [M]⇇CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 → [M]-CR2 → [M]-CR → [M]-C. This review includes some work on uranium and cerium complexes, but it does not present a complete coverage of actinide and lanthanide complexes with carbone or carbide ligands. |
| Starting Page | 4943 |
| e-ISSN | 14203049 |
| DOI | 10.3390/molecules25214943 |
| Journal | Molecules |
| Issue Number | 21 |
| Volume Number | 25 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2020-10-26 |
| Access Restriction | Open |
| Subject Keyword | Molecules Inorganic Chemistry Carbone Complexes Carbido Complexes Transition Metal Complexes Chemical Bonding |
| Content Type | Text |
| Resource Type | Article |
